New Mechanistic Insight into Stepwise Metal-Center Exchange in a Metal-Organic Framework Based on Asymmetric Zn4Clusters

2014 ◽  
Vol 20 (10) ◽  
pp. 2945-2952 ◽  
Author(s):  
Wei Meng ◽  
Huijun Li ◽  
Zhouqing Xu ◽  
Shanshan Du ◽  
Yunxia Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Center ◽  
Mechanistic Insight ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

Investigating the crystal engineering of the pillared paddlewheel metal–organic framework Zn2(NH2BDC)2DABCO

CrystEngComm ◽  
2018 ◽  
Vol 20 (39) ◽  
pp. 6082-6087 ◽  
Author(s):  
D. T. McGrath ◽  
V. A. Downing ◽  
M. J. Katz
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Framework ◽  
Mechanistic Insight ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

We examined the characterization data for Zn2(NH2BDC)2DABCO to gain mechanistic insight into the crystal engineering of pillared paddlewheel MOFs.

H3O2 Bridging Ligand in a Metal–Organic Framework. Insight into the Aqua-Hydroxo↔Hydroxyl Equilibrium: A Combined Experimental and Theoretical Study

2013 ◽  
Vol 135 (15) ◽  
pp. 5782-5792 ◽  
Author(s):  
Richard F. D’Vries ◽  
Victor A. de la Peña-O’Shea ◽  
Natalia Snejko ◽  
Marta Iglesias ◽  
Enrique Gutiérrez-Puebla ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Metal Organic Framework ◽  
Bridging Ligand ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

Molecular Insight into Fluorocarbon Adsorption in Pore Expanded Metal–Organic Framework Analogs

2020 ◽  
Vol 142 (6) ◽  
pp. 3002-3012 ◽  
Author(s):  
Jian Zheng ◽  
Dushyant Barpaga ◽  
Benjamin A. Trump ◽  
Manish Shetty ◽  
Yanzhong Fan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Expanded Metal ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

scholarly journals Kinetics of cooperative CO2 adsorption in diamine-appended variants of the metal–organic framework Mg2(dobpdc)

2020 ◽  
Vol 11 (25) ◽  
pp. 6457-6471 ◽  
Author(s):  
Jeffrey D. Martell ◽  
Phillip J. Milner ◽  
Rebecca L. Siegelman ◽  
Jeffrey R. Long
Keyword(s):  
Adsorption Kinetics ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Performance Properties ◽  
Metal Organic ◽  
Kinetics Of ◽  
Insight Into ◽  
Organic Framework

An in-depth investigation of the CO2 adsorption kinetics of a promising class of cooperative carbon capture materials offers new insight into their structure-performance properties.

The mechanism of MOF as the heterogeneous catalyst for propene hydroformylation: The DFT study

2022 ◽  
Author(s):  
Yifei Chen ◽  
Yang Gao ◽  
Lingtao Wang ◽  
Hao Gong
Keyword(s):  
Metal Complex ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Metal Center ◽  
Dft Study ◽  
Complex Catalyst ◽  
Metal Complex Catalyst ◽  
Metal Organic ◽  
Organic Framework

Metal-organic framework which was composed of metal center and organic linkers possessing the similar structure with the homogeneous metal-complex catalyst for hydroformylation, thus it could be potentially used as the...

A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

2019 ◽  
Vol 55 (98) ◽  
pp. 14781-14784 ◽  
Author(s):  
Ning-Yu Huang ◽  
Xue-Wen Zhang ◽  
Yu-Zhi Xu ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Metal Center ◽  
High Catalytic Activity ◽  
Methylene Groups ◽  
Metal Organic ◽  
Repulsive Forces ◽  
Organic Framework

The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.

Water interactions in metal organic frameworks

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 247-260 ◽  
Author(s):  
Kui Tan ◽  
Nour Nijem ◽  
Yuzhi Gao ◽  
Sebastian Zuluaga ◽  
Jing Li ◽  
...  
Keyword(s):  
Structural Variation ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

Insight into the structural variation of metal organic framework materials upon hydration.

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