scholarly journals Sodium Ion Batteries: Toward High Energy Density All Solid‐State Sodium Batteries with Excellent Flexibility (Adv. Energy Mater. 12/2020)

2020 ◽  
Vol 10 (12) ◽  
pp. 2070055
Author(s):  
Yu Yao ◽  
Zhenyao Wei ◽  
Haiyun Wang ◽  
Huijuan Huang ◽  
Yu Jiang ◽  
...  
Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 1000 ◽  
Author(s):  
Rui Liu ◽  
Ziteng Liang ◽  
Yuxuan Xiang ◽  
Weimin Zhao ◽  
Haodong Liu ◽  
...  

Na3V(PO4)2 was reported recently as a novel cathode material with high theoretical energy density for Sodium-ion batteries (SIBs). However, whether V3+/V4+/V5+ multielectron reactions can be realized during the charging process is still an open question. In this work, Na3V(PO4)2 is synthesized by using a solid-state method. Its atomic composition and crystal structure are verified by X-ray diffraction (XRD) and neutron diffraction (ND) joint refinement. The electrochemical performance of Na3V(PO4)2 is evaluated in two different voltage windows, namely 2.5–3.8 and 2.5–4.3 V. 51V solid-state NMR (ssNMR) results disclose the presence of V5+ in Na2−xV(PO4)2 when charging Na3V(PO4)2 to 4.3 V, confirming Na3V(PO4)2 is a potential high energy density cathode through realization of V3+/V4+/V5+ multielectron reactions.


Author(s):  
Jiefei Liu ◽  
Kangshou Lin ◽  
Yu Zhou ◽  
Yu Zhou ◽  
Xianhua Hou ◽  
...  

The sodium super ionic conductor (NASICON) materials are considered as the attractive cathode in sodium-ion batteries. Although the three-electron reactions in Na3MnTi(PO4)3 have greatly enhanced the capacity of NASICON-structure materials,...


2018 ◽  
Vol 5 (23) ◽  
pp. 1801342 ◽  
Author(s):  
Sanghyeon Kim ◽  
Xiangming Li ◽  
Lingzi Sang ◽  
Young Soo Yun ◽  
Ralph G. Nuzzo ◽  
...  

ACS Nano ◽  
2018 ◽  
Vol 12 (3) ◽  
pp. 2809-2817 ◽  
Author(s):  
Hongli Wan ◽  
Jean Pierre Mwizerwa ◽  
Xingguo Qi ◽  
Xin Liu ◽  
Xiaoxiong Xu ◽  
...  

Author(s):  
Chenrui Zhang ◽  
Tingting Liang ◽  
Huilong Dong ◽  
Junjun Li ◽  
Junyu Shen ◽  
...  

Sodium-ion batteries (SIBs) have been considered as promising candidates for large-scale energy storage. However, viable anode materials still suffer from sluggish electrochemical reaction kinetics and huge volume expansion during cycling,...


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