Enhanced propylene/propane separation in facilitated transport membranes containing multi‐silver complex

AIChE Journal ◽  
2021 ◽  
Author(s):  
Yafei Su ◽  
Shenzhen Cong ◽  
Meixia Shan ◽  
Yatao Zhang
1985 ◽  
Vol 17 (9) ◽  
pp. 1-12 ◽  
Author(s):  
Carl G. Enfield

Relatively immobile chemicals have been observed moving significantly faster than anticipated from hydrophobic theory. A theory is developed considering transport in three mobile fluid phases which can be used to describe this facilitated transport. The convective dispersive transport equation is solved utilizing a transformation of variables which permits utilizing existing solutions covering a wide variety of boundary conditions. The impact of the facilitated transport is demonstrated for one case where the soils organic carbon is 10%. If 2% of the fluid phase is an organic fraction, the theory developed projects that hydrophobic theory may underestimate mobility by more than 100 times. At concentrations of dissolved organic carbon normally observed in nature (5 - 10 mg/l), a measurable increased mobility is anticipated for the very immobile compounds like dioxins.


2021 ◽  
pp. 174751982198965
Author(s):  
Guoqi Zhang

( E)-4-[2-(Pyridin-4-yl)vinyl]benzaldehyde, containing both a 4-vinylpyridine and an aldehyde functionality, is utilized to develop new, highly conjugated chalcone compounds and a bis-Schiff base azine compound. The chalcone-containing compounds are further explored for their protonation, methylation and silver(I) coordination chemistry using the pyridine moiety. In parallel, a cyano-containing analogue, ( E)-4-[2-(pyridin-4-yl)vinyl]benzonitrile is also synthesized and studied for its silver(I) coordination chemistry. These new compounds are fully characterized by mass spectrometry, elemental analysis and spectroscopic techniques. The methylated product of ( E)-1-(9-anthryl)-3-{4-[2-(pyridin-4-yl)vinyl]phenyl}prop-2-en-1-one and a silver complex of ( E)-4-[2-(pyridin-4-yl)vinyl]benzonitrile are structurally determined by X-ray crystallography.


2020 ◽  
pp. 119007
Author(s):  
S. Kunalan ◽  
Kalyan Dey ◽  
Projesh Kumar Roy ◽  
Vasumathi Velachi ◽  
Prabal Kumar Maiti ◽  
...  

1995 ◽  
Vol 100 (2) ◽  
pp. 99-109 ◽  
Author(s):  
P. Lacan ◽  
C. Guizard ◽  
P. Le Gall ◽  
D. Wettling ◽  
L. Cot

2013 ◽  
Vol 1049 ◽  
pp. 1-6 ◽  
Author(s):  
Irlene Maria Pereira e Silva ◽  
Daniel de Moraes Profirio ◽  
Raphael Enoque Ferraz de Paiva ◽  
Marcelo Lancellotti ◽  
André Luiz Barboza Formiga ◽  
...  

2009 ◽  
Vol 150 (1) ◽  
pp. 83-89 ◽  
Author(s):  
Weidong Zhang ◽  
Junteng Liu ◽  
Zhongqi Ren ◽  
Shuguang Wang ◽  
Changshun Du ◽  
...  

2009 ◽  
Vol 337 (1-2) ◽  
pp. 224-231 ◽  
Author(s):  
Gulsin Arslan ◽  
Ali Tor ◽  
Harun Muslu ◽  
Mustafa Ozmen ◽  
Ilker Akin ◽  
...  

2001 ◽  
Vol 17 (4) ◽  
pp. 477-479 ◽  
Author(s):  
Aparna SIL ◽  
Vijaykumar S. IJERI ◽  
Ashwini K. SRIVASTAVA

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