A heterometal (Pd-Pb) organic framework: synthesis, structure and heterogeneous catalytic application

A Zn(ii) metallacycle [Zn2{(L)2(DMF)2(NO3)2}]·(NO3)2 (1) along with a Cd(ii) coordination polymer [{Cd(L)2(DMF)2}·(NO3)2]n (2) have been synthesized, structurally characterized and exploited as a multifunctional material.

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Hydrothermal synthesis, structure, heterogeneous catalytic activity and photoluminescent properties of a novel homoleptic Sm(III)-organic framework

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2016.09.018 ◽

2016 ◽

Vol 244 ◽

pp. 61-68 ◽

Cited By ~ 15

Author(s):

Burak Ay ◽

Emel Yildiz ◽

Ashley C. Felts ◽

Khalil A. Abboud

Keyword(s):

Catalytic Activity ◽

Hydrothermal Synthesis ◽

Heterogeneous Catalytic ◽

Organic Framework

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The synthesis, structure, topology and catalytic application of a novel cubane-based copper(ii) metal–organic framework derived from a flexible amido tripodal acid

Dalton Transactions ◽

10.1039/c4dt03087g ◽

2015 ◽

Vol 44 (22) ◽

pp. 10156-10165 ◽

Cited By ~ 48

Author(s):

Anirban Karmakar ◽

Clive L. Oliver ◽

Somnath Roy ◽

Lars Öhrström

Keyword(s):

Metal Organic Framework ◽

Flexible Ligand ◽

Structure Topology ◽

Catalytic Application ◽

Metal Organic ◽

Organic Framework

A novel chiral metal–organic framework, [Cu4(HL)2(H2O)4(MeO)4]n (1), has been successfully synthesized from a tripodal flexible ligand (2S,2′S,2′′S)-2,2′,2′′-(benzenetricarbonyltris(azanediyl))tripropanoic acid.

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Synthesis and catalytic application in isobutane dehydrogenation of the mesoporous chromia/alumina catalysts based on a metal–organic framework

Microporous and Mesoporous Materials ◽

10.1016/j.micromeso.2013.07.024 ◽

2013 ◽

Vol 181 ◽

pp. 182-191 ◽

Cited By ~ 20

Author(s):

Huahua Zhao ◽

Huanling Song ◽

Lingjun Chou

Keyword(s):

Metal Organic Framework ◽

Isobutane Dehydrogenation ◽

Catalytic Application ◽

Metal Organic ◽

Alumina Catalysts ◽

Organic Framework

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N-Heterocyclic Carbene Functionalized Covalent Organic Framework for Transesterification of Glycerol with Dialkyl Carbonates

Catalysts ◽

10.3390/catal11040423 ◽

2021 ◽

Vol 11 (4) ◽

pp. 423

Author(s):

Yuying Chai ◽

Yaling Li ◽

Hui Hu ◽

Chaoyuan Zeng ◽

Shenglin Wang ◽

...

Keyword(s):

Catalytic Activity ◽

Heterogeneous Catalyst ◽

Active Sites ◽

Covalent Organic Framework ◽

Heterogeneous Catalytic ◽

Dialkyl Carbonates ◽

Dialkyl Carbonate ◽

Catalytic Active Sites ◽

Catalytic Reactivity ◽

Organic Framework

The development of a heterogeneous catalyst through the combination of novel carrier and powerful catalytic active sites is of particular interest. Herein, the successful integration of an N-Heterocyclic carbene (NHC) moiety into a covalent organic framework (COF) was achieved by coupling 4,4′,4′′,4′′′-(pyrene-1,3,6,8-tetrayl) tetraaniline (PyTTA) and equimolar 5,6-bis(4-formylphenyl)-1-methyl-1H-benzimidazole (IM) and 2′3′5′6′-tetrafluoro-[1,1′:4′,1′′-terphenyl]-4,4′-dicarbaldehyde (4F) followed by ionization with 1-bromobutane (C4H9Br) and then deprotonation upon addition of a base. The resulting material exhibited promising heterogeneous catalytic activity towards transesterification reaction of glycerol with dialkyl carbonate. Moreover, good recyclability granted no substantial loss of activity upon five cycles. Combination of COFs and NHCs might synergize their characteristics, thus providing more possibilities for creating new patterns of catalytic reactivity.

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