Studies on synthetic-polymer plates with high surface energy. IV. Determination of critical surface tension with aqueous solutions of salts

1982 ◽  
Vol 27 (8) ◽  
pp. 3161-3169
Author(s):  
Norio Kaneko ◽  
Yasuji Ohtsuka
2019 ◽  
Vol 394 ◽  
pp. 1-4
Author(s):  
Valentina Ivanovna Loganina ◽  
Yerkebulan Bisengalievich Mazhitov ◽  
Yuri Petrovich Skachkov

The results of the study provide information on the resistance of coatings based on the solof silicate paint in the process of freezing and thawing. It was found, that coatings based on sol silicatepaints are characterized by a higher resistance compared of silicate coatings. It is shown, that thecoatings withstood 50 cycles of alternate freezing and thawing. The surface energy of the coatingswas calculated using the critical surface tension of the fluid at the interface with the solid. Thedispersion contribution in the intermolecular interaction between the particles of the coatings wasestimated. The values of the surface tension of the coatings and the values of the dispersioncomponent of the surface energy of the coatings — the complex Hamaker constant — are calculated.It was revealed, that after testing a decrease in the values of the Hamaker constant is observed. It wasestablished, that after testing for frost resistance, the values of the Hamaker constant for coatingsbased on sol of silicate paint are higher compared to coatings based on silicate paint.


Author(s):  
Joanna Krawczyk

AbstractWettability of poly(tetrafluoroethylene) (PTFE) by aqueous solutions of binary mixtures composed of sodium bis(2-ethylhexyl) sulfosuccinate (AOT) with polyoxyethylene (23) lauryl ether (Brij 35) was considered on the basis of the measured values of contact angle and surface tension. It was shown that the value of the critical surface tension of PTFE surface wetting at the studied system (23.5 mN/m), does not depend on the concentration and composition of the binary mixtures of studied surfactants in water, and it was higer than the surface tension of PTFE (20.2 mN/m). The best wettability of polytetrafluoroethylene (PTFE) by studied aqueous solutions of binary surfactants mixtures occurs at the mixtures concentration corresponding to the critical micelle concentration of their solutions.


2016 ◽  
Vol 23 (03) ◽  
pp. 1650009 ◽  
Author(s):  
İ. A. KARIPER

This study examines the critical surface energy of manganese sulfite (MnSO[Formula: see text] crystalline thin film, produced via chemical bath deposition (CBD) on substrates. In addition, parachor, which is an important parameter of chemical physics, and its relationship with grain size, film thickness, etc., has been investigated for thin films. For this purpose, MnSO3 thin films were deposited at room temperature using different deposition times. Structural properties of the films, such as film thickness and average grain size, were examined using X-ray diffraction; film thickness and surface properties were measured by and atomic force microscope; and critical surface tension of MnSO3 thin films was measured with Optical Tensiometer and calculated using Zisman method. The results showed that critical surface tension and parachor of the films have varied with average grain size and film thickness. Critical surface tension was calculated as 32.97, 24.55, 21.03 and 12.76[Formula: see text]mN/m for 14.66, 30.84, 37.07 and 44.56[Formula: see text]nm grain sizes, respectively. Film thickness and average grain size have been increased with the deposition time and they were found to be negatively correlated with surface tension and parachor. The relationship between film thickness and parachor was found as [Formula: see text] whereas the relationship between average grain size and parachor was found as [Formula: see text] We also showed the relationships between parachor and some thin films parameters.


1971 ◽  
Vol 36 (3) ◽  
pp. 298-307 ◽  
Author(s):  
H.L Rosano ◽  
W Gerbacia ◽  
M.E Feinstein ◽  
J.W Swaine

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