Rheological, mechanical and morphological properties of thermoplastic vulcanizates based on high impact polystyrene and styrene-butadiene rubber

2010 ◽  
pp. NA-NA ◽  
Author(s):  
Zhaobo Wang ◽  
Hongling Zhao ◽  
Jian Zhao ◽  
Xin Wang
2010 ◽  
Vol 2 (2) ◽  
Author(s):  
Dwi Wahyuni

High impact polystyrene (HIPS) is the widely used material now, and also for the aerospace material as a communication instrument system and an electrical insulation. In order to produce HIPS, there are a view method which can be executed. In this case, the research is executed by the copolymerization processes of styrene butadiene rubber (SBR) solution in styrene. Variables which influence to the result properties (HIPS) are the SBR to styrene ratio, the solvent (ethyl benzene), the benzoyl peroxide initiator (BPO). The properties of the product are tensile strength, impact strength, softening point, melting point and the hardness. The result showed that the properties of the HIPS product was near of the HIPS high heat. The optimal processes condition was the solvent to the styrene monomer ratio was 0.05492, the SBR to the styrene ratio was 0.1236 and the BPO to the styrene ratio was 0,0003. The properties of the HIPS product were: the impact strength was (519-1215) N per cm, the tensil strength not more than was 106 N per cm, the elongation was (36-54) percent and the hardness was (65-69) shore A. This properties achieved at the mixing polymerization processes 4 scale in 11-12 hours, the early mixing at 4 scale 1 hours, the cutting chain 2 drops.


2013 ◽  
Vol 795 ◽  
pp. 119-123
Author(s):  
Ahmad Azmi Azrem ◽  
N.Z. Noriman ◽  
M.N. Razif ◽  
S.T. Sam ◽  
M.S. Saiful Nizwan

The effects of physical and morphological properties of styrene butadiene rubber/virgin chloroprene rubber blends (SBR/CRv) and styrene butadiene rubber/recycled chloroprene rubber blends (SBR/CRr) were investigated. Both SBR/CRv blends and SBR/CRr blends were prepared using two roll mill at room temperature with blend ratios 95/5, 85/15, 75/25, 65/35 and 50/50. The range size of CRr used in this study was 0.3 0.7 mm. The SBR/CRr blends shows higher value of hardness and crosslink density compared to SBR/CRv blends at all blend ratios. The scanning electron microscopy (SEM) of tensile fracture surface of SBR/CRr blends at 15 blend ratio illustrated a better adhesion and dispersion of CRr with SBR matrix compared with SBR/CRv blends.


2013 ◽  
Vol 594-595 ◽  
pp. 862-866 ◽  
Author(s):  
Ahmad Azmi Azrem ◽  
N.Z. Noriman ◽  
M.N. Razif ◽  
S.T. Sam

Elastomer blends are widely used in rubber products for a variety of reasons, which include improved physical properties, improved service life, easier processing, and reduced production cost [. Butadiene and chloroprene (2-chloro-1,3 butadiene) are related monomers [. Blending of SBR with CR has been done to obtain better crystallisation resistance, better compression set resistance, lower brittleness temperature and enhanced resistance to sunlight deterioration as compared with CR alone. Other important properties, such as oil, heat, flame and ozone resistance, decrease as the amount of SBR increases [. It is possible to improve the phase morphology of SBR/CR blend by incorporating 5±10 phr of a modified copolymer that has segments chemically identical to SBR and CR phases. Addition of halocarbenes to polymers has been reported since a long time; however, available information on the commercial application on such modified polymers is limited [.


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