The coordination chemistry of lanthanide and actinide metal ions with hydroxypyridinone-based decorporation agents: orbital and density based analyses

2018 ◽  
Vol 47 (46) ◽  
pp. 16603-16615 ◽  
Author(s):  
Biswajit Sadhu ◽  
Vijayakriti Mishra
Keyword(s):  
Charge Transfer ◽  
Coordination Chemistry ◽  
Metal Ions ◽  
Metal Charge ◽  
Topological Constraints ◽  
Orbital Mixing ◽  
Actinide Ions ◽  
Metal Charge Transfer

Ligand-to-metal charge transfer, orbital-mixing, chelatoaromatic effect and topological constraints control the binding of lanthanide and actinide ions to hydroxypyridinone-based decorporation agents.

Ligand(s)-to-metal charge transfer as a factor controlling the equilibrium constants of late first-row transition metal complexes: revealing the Irving–Williams thermodynamical series

2015 ◽  
Vol 17 (2) ◽  
pp. 805-811 ◽  
Author(s):  
Pradeep R. Varadwaj ◽  
Arpita Varadwaj ◽  
Bih-Yaw Jin
Keyword(s):  
Charge Transfer ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Equilibrium Constants ◽  
Bivalent Metal ◽  
Metal Charge ◽  
Bivalent Metal Ions ◽  
Metal Charge Transfer

Ligand(s)-to-metal charge transfer obtained from QTAIM charges unravel the Irving–William series for the equilibrium constants of late first-row bivalent metal ions.

Tuning metal to metal charge transfer properties in cyanidometal-bridged complexes by changing the auxiliary ligand on the bridge

2021 ◽  
Author(s):  
Qing-Dou Xu ◽  
Chen Zeng ◽  
Shao-Dong Su ◽  
Yu-Ying Yang ◽  
Sheng-Min Hu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Auxiliary Ligand ◽  
Metal Charge ◽  
Transfer Properties ◽  
Metal Charge Transfer

This work shows that the energy of MMCT in cyanidometal-bridged complexes can be tuned systematically by changing the auxiliary ligand of the cyanidometal bridge.

The fluorescence properties of tiara like structural thiolated palladium clusters

2017 ◽  
Vol 46 (38) ◽  
pp. 12964-12970 ◽  
Author(s):  
Jishi Chen ◽  
Yanze Pan ◽  
Zonghua Wang ◽  
Peng Zhao
Keyword(s):  
Charge Transfer ◽  
Fluorescence Properties ◽  
Metal Charge ◽  
Palladium Clusters ◽  
Metal Charge Transfer

A series of tiara like structural Pdn(SR)2n (5 ≤ n ≤ 20) nanoclusters exhibit emission at 620 nm with excitation at around 268 nm. Their emission is due to ligand to metal charge transfer.

Sign in / Sign up

Export Citation Format

Share Document