ChemInform Abstract: INTERACTION OF PHTHALOCYANINATOIRON(II) WITH MOLECULAR OXYGEN. KINETICS AND MECHANISM OF THE REACTION IN DIMETHYL SULFOXIDE

1983 ◽  
Vol 14 (46) ◽  
Author(s):  
C. ERCOLANI ◽  
G. ROSSI ◽  
F. MONACELLI ◽  
M. VERZINO
Keyword(s):  
Dimethyl Sulfoxide ◽  
Molecular Oxygen ◽  
Kinetics And Mechanism ◽  
Oxygen Kinetics ◽  
Mechanism Of The Reaction

Kinetics and mechanism of the reaction of vinyl radicals with molecular oxygen

1984 ◽  
Vol 104 (5) ◽  
pp. 469-474 ◽  
Author(s):  
Jong-Yoon Park ◽  
Michael C. Heaven ◽  
David Gutman
Keyword(s):  
Molecular Oxygen ◽  
Kinetics And Mechanism ◽  
Vinyl Radicals ◽  
Mechanism Of The Reaction

Aromatic Substitutions with Carbanion Nucleophiles. II. The Kinetics and Mechanism of the Reaction of 1-Fluoro-2,4-dinitrobenzene with the Diethyl Malonate Anion

1973 ◽  
Vol 51 (10) ◽  
pp. 1659-1664 ◽  
Author(s):  
Kenneth T. Leffek ◽  
Paul H. Tremaine
Keyword(s):  
Dimethyl Sulfoxide ◽  
Sodium Salt ◽  
Rate Constants ◽  
Activation Parameters ◽  
Diethyl Malonate ◽  
Kinetics And Mechanism ◽  
Reaction Solution ◽  
Red Color ◽  
Unstable Intermediate ◽  
Mechanism Of The Reaction

The reaction of fluoro-2,4-dinitrobenzene with the sodium salt of diethyl malonate to form diethyl (2,4-dinitrophenyl)malonate is fast in dimethyl sulfoxide solvent. The stable red color of the reaction solution is due to the anion of the product, although the initially formed unstable intermediate between the substrate and the anion nucleophile is also red and can be observed at times less than 200 ms after mixing.The rate constants for all the steps in the reaction have been measured and the activation parameters for the three processes involved in the nucleophile substitution have been calculated.

The kinetics and mechanism of the reaction between nickel(II) and dithiocarbamate ions in dimethyl sulfoxide. Evidence for the ID mechanism for a bidentate uninegative ligand

1978 ◽  
Vol 31 (12) ◽  
pp. 2581 ◽  
Author(s):  
PJ Nichols ◽  
MW Grant
Keyword(s):  
Fourier Transform ◽  
Ionic Strength ◽  
Dimethyl Sulfoxide ◽  
Excellent Agreement ◽  
Rate Constants ◽  
Second Order ◽  
Kinetics And Mechanism ◽  
First Order ◽  
Temperature Dependences ◽  
Mechanism Of The Reaction

13C Fourier-transform N.M.R. has been used to measure the rate of exchange of dimethyl sulfoxide with hexakis(dimethyl sulfoxide)nickel(II) cation. The parameters obtained, kex(25°C)(9.8�4.6) × 103 s-1, ΔH‡ 50�2 kJ mol-1 and ΔS‡ 0�4 J K-1 mol-1, are in excellent agreement with those of the most recent 1H N.M.R. study. The reaction between Ni(Me2SO)62+ and diethyldithiocarbamate (dtc-) gives only Ni(dtc)2. When dtc- is in excess, the rate of formation of Ni(dtc)2 is first order in Ni2+ and dtc-. The ionic-strength and temperature dependences of the second-order rate constants are consistent with the rate-determining formation of an unstable Ni(dtc)+ complex by an ID mechanism.

Kinetics and mechanism of the reaction of cyanocobalamin with potassium hydroxide in non-aqueous media

2019 ◽  
Vol 43 (20) ◽  
pp. 7708-7715
Author(s):  
D. S. Salnikov ◽  
S. V. Makarov
Keyword(s):  
Dimethyl Sulfoxide ◽  
Potassium Hydroxide ◽  
Isopropyl Alcohol ◽  
Aqueous Media ◽  
Kinetics And Mechanism ◽  
Anaerobic Conditions ◽  
Mechanism Of The Reaction

The reaction of cyanocobalamin (CNCbl) with potassium hydroxide (KOH) was studied in isopropyl alcohol (iPrOH) and dimethyl sulfoxide (DMSO) under anaerobic conditions.

ChemInform Abstract: Structure and Reactivity of (PPh4)3[W(CN)5O]×7H2O. Kinetics and Mechanism of the Reaction with Molecular Oxygen.

ChemInform ◽  
2010 ◽  
Vol 32 (47) ◽  
pp. no-no
Author(s):  
Janusz Szklarzewicz ◽  
Dariusz Matoga ◽  
Alina Samotus ◽  
John Burgess ◽  
John Fawcett ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Kinetics And Mechanism ◽  
Abstract Structure ◽  
Mechanism Of The Reaction
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