ChemInform Abstract: Oxidative Carbonylation of Aniline Over Pd/C Catalyst: Effect of Promoters, Solvents, and Reaction Conditions.

ChemInform ◽  
1989 ◽  
Vol 20 (14) ◽  
Author(s):  
S. P. GUPTE ◽  
R. V. CHAUDHARI
2019 ◽  
Vol 193 ◽  
pp. 263-272 ◽  
Author(s):  
G.M. Cabello González ◽  
P. Concepción ◽  
A.L. Villanueva Perales ◽  
A. Martínez ◽  
M. Campoy ◽  
...  

Fuel ◽  
2008 ◽  
Vol 87 (17-18) ◽  
pp. 3483-3489 ◽  
Author(s):  
Nianjun Luo ◽  
Xianwen Fu ◽  
Fahai Cao ◽  
Tiancun Xiao ◽  
Peter P. Edwards

2022 ◽  
Vol 226 ◽  
pp. 107092
Author(s):  
G.M. Cabello González ◽  
A.L. Villanueva Perales ◽  
A. Martínez ◽  
M. Campoy ◽  
F. Vidal-Barrero

2002 ◽  
Vol 19 (4) ◽  
pp. 607-610 ◽  
Author(s):  
Xing-Dong Yuan ◽  
Jung-Nam Park ◽  
Jun Wang ◽  
Chul Wee Lee ◽  
Sang-Eon Park

Catalysts ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1483
Author(s):  
Marthinus Rudi Swart ◽  
Charlene Marais ◽  
Elizabeth Erasmus

The metathesis of 1-hexene and (E)-anethole in the presence of Grubbs 2nd generation catalyst was monitored by in situ 1H NMR spectroscopy at different temperatures (15 °C, 25 °C, and 45 °C) and anethole mol fractions (XAnethole ≈ 0.17, 0.29, 0.5, 0.71, 0.83). Time traces confirmed the instantaneous formation of (E)-1-(4-methoxyphenyl)-1-hexene, the cross-metathesis product. A maximum concentration of (E)-1-(4-methoxyphenyl)-1-hexene is reached fairly fast (the time depending on the reaction conditions), and this is followed by a decrease in the concentration of (E)-1-(4-methoxyphenyl)-1-hexene due to secondary metathesis. The maximum concentration of (E)-1-(4-methoxyphenyl)-1-hexene was more dependent on the XAnethole than the temperature. The highest TOF (3.46 min−1) was obtained for the reaction where XAnethole was 0.16 at 45 °C. The highest concentration of the cross-metathesis product was however achieved after 6 min with an anethole mol fraction of 0.84 at 25 °C. A preliminary kinetic study indicated that the secondary metathesis reaction followed first order kinetics.


2003 ◽  
Vol 37 (4) ◽  
pp. 793-800 ◽  
Author(s):  
Shiow Shyung Lin ◽  
Dong Jang Chang ◽  
Ching-Huei Wang ◽  
Chia Chrn Chen

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