ChemInform Abstract: Cyanuric Chloride Catalyzed Beckmann Rearrangement of Ketoximes in Biodegradable Ionic Liquids.

ChemInform ◽  
2012 ◽  
Vol 43 (26) ◽  
pp. no-no
Author(s):  
Angelamaria Maia ◽  
Domenico C. M. Albanese ◽  
Dario Landini
Synlett ◽  
2008 ◽  
Vol 2008 (6) ◽  
pp. 908-910 ◽  
Author(s):  
Dario Landini ◽  
Angelamaria Maia ◽  
Cecilia Betti ◽  
Maurizio Pasi

Tetrahedron ◽  
2012 ◽  
Vol 68 (7) ◽  
pp. 1947-1950 ◽  
Author(s):  
Angelamaria Maia ◽  
Domenico C.M. Albanese ◽  
Dario Landini

ChemInform ◽  
2008 ◽  
Vol 39 (32) ◽  
Author(s):  
Cecilia Betti ◽  
Dario Landini ◽  
Angelamaria Maia ◽  
Maurizio Pasi

Author(s):  
Tong Shen-Yue ◽  
Lu Jue-Lin ◽  
Li Xiao-Wen ◽  
NI Wan-Min ◽  
Xu Ke-Wei ◽  
...  

In order to find an efficient catalytic system for Beckmann rearrangement of ketoximes, cyanuric chloride and Lewis acids were screened, and the cyanuric chloride /manganese chloride tetrahydrate system with good catalytic effect has been discovered. Using 2 mol% cyanuric chloride and 2 mol% MnCl2·4H2O as catalyst, the yield of Beckmann rearrangement of benzophenone oxime was 96% after refluxing for 2 h in acetonitrile. A variety of ketoximes underwent the Beckmann rearrangement to afford the corresponding amides in moderate to high yields.


2021 ◽  
Vol 41 (2) ◽  
pp. 688
Author(s):  
Tingting Zhou ◽  
Xia Liu ◽  
Zihang Ye ◽  
Yipeng Zhou ◽  
Yaqi Yang ◽  
...  

2001 ◽  
Vol 42 (3) ◽  
pp. 403-405 ◽  
Author(s):  
Jiajian Peng ◽  
Youquan Deng

Sign in / Sign up

Export Citation Format

Share Document