scholarly journals Cyanuric Chloride Catalysis and Solvent Effect Leading to a Mild and Efficient Beckmann Rearrangement of Ketoximes

2021 ◽  
Vol 41 (2) ◽  
pp. 688
Author(s):  
Tingting Zhou ◽  
Xia Liu ◽  
Zihang Ye ◽  
Yipeng Zhou ◽  
Yaqi Yang ◽  
...  
Keyword(s):  
Solvent Effect ◽  
Beckmann Rearrangement ◽  
Cyanuric Chloride

Beckmann Rearrangement of Oximes Catalyzed by Cyanuric Chloride in Ionic Liquids

Synlett ◽  
2008 ◽  
Vol 2008 (6) ◽  
pp. 908-910 ◽  
Author(s):  
Dario Landini ◽  
Angelamaria Maia ◽  
Cecilia Betti ◽  
Maurizio Pasi
Keyword(s):  
Ionic Liquids ◽  
Beckmann Rearrangement ◽  
Cyanuric Chloride

scholarly journals Cyanuric Chloride / Manganese Chloride Tetrahydrate Catalyzed Beckmann Rearrangement of Ketoximes

2019 ◽  
pp. 1-6
Author(s):  
Tong Shen-Yue ◽  
Lu Jue-Lin ◽  
Li Xiao-Wen ◽  
NI Wan-Min ◽  
Xu Ke-Wei ◽  
...  
Keyword(s):  
Catalytic System ◽  
Lewis Acids ◽  
Catalytic Effect ◽  
Beckmann Rearrangement ◽  
Cyanuric Chloride ◽  
Manganese Chloride ◽  
Manganese Chloride Tetrahydrate ◽  
High Yields

In order to find an efficient catalytic system for Beckmann rearrangement of ketoximes, cyanuric chloride and Lewis acids were screened, and the cyanuric chloride /manganese chloride tetrahydrate system with good catalytic effect has been discovered. Using 2 mol% cyanuric chloride and 2 mol% MnCl2·4H2O as catalyst, the yield of Beckmann rearrangement of benzophenone oxime was 96% after refluxing for 2 h in acetonitrile. A variety of ketoximes underwent the Beckmann rearrangement to afford the corresponding amides in moderate to high yields.

A New Look at the Classical Beckmann Rearrangement:  A Strong Case of Active Solvent Effect

1997 ◽  
Vol 119 (10) ◽  
pp. 2552-2562 ◽  
Author(s):  
Minh Tho Nguyen ◽  
Greet Raspoet ◽  
Luc G. Vanquickenborne
Keyword(s):  
Solvent Effect ◽  
Beckmann Rearrangement ◽  
Strong Case ◽  
Active Solvent ◽  
New Look

Solvent effect on the kinetics of Beckmann rearrangement

2010 ◽  
Vol 80 (1) ◽  
pp. 31-34 ◽  
Author(s):  
G. G. Midyana ◽  
R. G. Makitra ◽  
E. Ya. Pal’chikova
Keyword(s):  
Solvent Effect ◽  
Beckmann Rearrangement ◽  
Kinetics Of

Beckmann rearrangement of ketoximes promoted by cyanuric chloride and dimethyl sulfoxide under a mild condition

2021 ◽  
Vol 63 ◽  
pp. 152707
Author(s):  
Ruonan Ma ◽  
Xueyuan Chen ◽  
Zhiyin Xiao ◽  
Mookan Natarajan ◽  
Chunxin Lu ◽  
...  
Keyword(s):  
Dimethyl Sulfoxide ◽  
Mild Condition ◽  
Beckmann Rearrangement ◽  
Cyanuric Chloride

ChemInform Abstract: Cyanuric Chloride Catalyzed Beckmann Rearrangement of Ketoximes in Biodegradable Ionic Liquids.

ChemInform ◽  
2012 ◽  
Vol 43 (26) ◽  
pp. no-no
Author(s):  
Angelamaria Maia ◽  
Domenico C. M. Albanese ◽  
Dario Landini
Keyword(s):  
Ionic Liquids ◽  
Beckmann Rearrangement ◽  
Cyanuric Chloride

Cyanuric chloride catalyzed Beckmann rearrangement of ketoximes in biodegradable ionic liquids

Tetrahedron ◽  
2012 ◽  
Vol 68 (7) ◽  
pp. 1947-1950 ◽  
Author(s):  
Angelamaria Maia ◽  
Domenico C.M. Albanese ◽  
Dario Landini
Keyword(s):  
Ionic Liquids ◽  
Beckmann Rearrangement ◽  
Cyanuric Chloride

Cyanuric Chloride as a Mild and Active Beckmann Rearrangement Catalyst

2005 ◽  
Vol 127 (32) ◽  
pp. 11240-11241 ◽  
Author(s):  
Yoshiro Furuya ◽  
Kazuaki Ishihara ◽  
Hisashi Yamamoto
Keyword(s):  
Beckmann Rearrangement ◽  
Cyanuric Chloride

scholarly journals Cyanuric Chloride as a Mild and Active Beckmann Rearrangement Catalyst.

ChemInform ◽  
2005 ◽  
Vol 36 (51) ◽  
Author(s):  
Yoshiro Furuya ◽  
Kazuaki Ishihara ◽  
Hisashi Yamamoto
Keyword(s):  
Beckmann Rearrangement ◽  
Cyanuric Chloride
Sign in / Sign up

Export Citation Format

Share Document