Improved H 2 SO 4 ‐catalyzed alkylation reaction in a rotating packed bed reactor by adding additives

Author(s):  
Yuntao Tian ◽  
Sijing Mei ◽  
Liang‐Liang Zhang ◽  
Guang‐wen Chu ◽  
Baochang Sun ◽  
...  
2017 ◽  
Vol 224 ◽  
pp. 292-297 ◽  
Author(s):  
Juntao Xu ◽  
Changsheng Liu ◽  
Meng Wang ◽  
Lei Shao ◽  
Li Deng ◽  
...  

2003 ◽  
Vol 58 (3-6) ◽  
pp. 569-575 ◽  
Author(s):  
Jian-Feng Chen ◽  
Lei Shao ◽  
Fen Guo ◽  
Xing-Ming Wang

2021 ◽  
Vol 11 (21) ◽  
pp. 10194
Author(s):  
Wenhui Hou ◽  
Wei Wang ◽  
Yang Xiang ◽  
Yingjiao Li ◽  
Guangwen Chu ◽  
...  

Polymerization of isobutylene (IB) for synthesizing highly reactive polyisobutylene (HRPIB) is characterized by a complicated fast intrinsic reaction rate; therefore, the features of its products exhibit a strong dependence on mixing efficiency. To provide uniform and efficient mixing, a rotating packed bed was employed as a reactor for polymerization of IB. The effects of operating parameters including polymerization temperature (T), rotating speed (N) and relative dosage of monomers and initiating systems ([M]0/[I]0) on number-average molecular weight (Mn) of HRPIB were studied. HRPIB with Mn of 2550 g·mol−1 and exo-olefin terminal content of 85 mol% were efficiently obtained at suitable conditions as T of 283 K, N of 1600 rpm and [M]0/[I]0 of 49. Moreover, the Mn can be regulated by changing T, N and [M]0/[I]0. Based on the presumptive-steady-state analysis method and the coalescence–redispersion model, a model for prediction of the Mn was developed and validated, and the calculated Mn values agreed well with experimental results, with a deviation of ±10%. The results demonstrate that RPB is a promising reactor for synthesizing HRPIB, and the given model for Mn can be applied for the design of RPB and process optimization.


2016 ◽  
Vol 55 (44) ◽  
pp. 11622-11630 ◽  
Author(s):  
Xing-Wei Han ◽  
Xiang-Zhen Meng ◽  
Jie Zhang ◽  
Jie-Xin Wang ◽  
Hai-Feng Huang ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (68) ◽  
pp. 63667-63680 ◽  
Author(s):  
S. Mosleh ◽  
M. R. Rahimi ◽  
M. Ghaedi ◽  
K. Dashtian ◽  
S. Hajati

BiPO4/Bi2S3-HKUST-1-MOF as a novel blue light active photocatalyst was synthesized and characterized by X-ray XRD, SEM, PL, BET, BJH and DRS.


AIChE Journal ◽  
2009 ◽  
pp. NA-NA ◽  
Author(s):  
Jian-Feng Chen ◽  
Hua Gao ◽  
Hai-Kui Zou ◽  
Guang-Wen Chu ◽  
Lei Zhang ◽  
...  

2019 ◽  
Vol 26 (4) ◽  
pp. 273-282 ◽  
Author(s):  
Qing Liu ◽  
Yuan Pu ◽  
Zhijian Zhao ◽  
Jiexin Wang ◽  
Dan Wang

AbstractWe developed the high-gravity coupled liquid–liquid interface reaction technique on the basis of the rotating packed bed (RPB) reactor for the continuous and ultrafast synthesis of silver sulfide (Ag2S) quantum dots (QDs) with near-infrared (NIR) luminescence. The formation of Ag2S QDs occurs at the interface of microdroplets, and the average size of Ag2S QDs was 4.5 nm with a narrow size distribution. Ag2S QDs can disperse well in various organic solvents and exhibit NIR luminescence with a peak wavelength at 1270 nm under 980-nm laser excitation. The mechanism of the process intensification was revealed by both the computational fluid dynamics simulation and fluorescence imaging, and the mechanism is attributed to the small and uniform droplet formation in the RPB reactor. This study provides a novel approach for the continuous and ultrafast synthesis of NIR Ag2S QDs for potential scale-up.


2021 ◽  
pp. 117147
Author(s):  
Zhang-Nan Wen ◽  
Yan-Bin Li ◽  
Wei Liu ◽  
Yong Luo ◽  
Liang-Liang Zhang ◽  
...  

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