Two‐step Thermal Annealing: An Effective Route for 15% Efficient Quasi‐2D Perovskite Solar Cells

ChemPlusChem ◽  
2021 ◽  
Author(s):  
Valentino Romano ◽  
Leyla Najafi ◽  
Albertus Sutanto ◽  
Giorgio Schileo ◽  
Valentin Queloz ◽  
...  
2020 ◽  
Vol 276 ◽  
pp. 128215 ◽  
Author(s):  
Blake Martin ◽  
Mengjin Yang ◽  
Rosemary C. Bramante ◽  
Eric Amerling ◽  
Gautam Gupta ◽  
...  

2021 ◽  
Vol 9 ◽  
Author(s):  
Robert T. Piper ◽  
Trey B. Daunis ◽  
Weijie Xu ◽  
Kurt A. Schroder ◽  
Julia W. P. Hsu

High-throughput roll-to-roll (R2R) manufacturing of perovskite solar cells (PSCs) is currently limited by thermal processes that take tens of minutes each, translating to impractically long annealing tools at high web speeds. In addition, PSCs are usually made with metal oxide transport layer materials that require high temperatures for thermal annealing. Here, we demonstrate the fabrication of PSCs using photonic curing, instead of thermal annealing, to convert NiOx directly from sol-gel precursors for hole transport layers and to crystallize methylammonium lead iodide (MAPbI3) active layers on flexible Willow® Glass substrates. Photonic curing uses short, intense pulses of light to process materials at a high speed, hence it is compatible with R2R manufacturing. We achieved power conversion efficiencies (PCEs) of 11.7% in forward-scan and 10.9% in reverse-scan for PSCs made with photonic cured NiOx and MAPbI3 films. Furthermore, both NiOx and MAPbI3 films could be processed with a single photonic curing pulse, with a web speed of 5.7 m/min, and still produce PCEs comparable to thermally annealed control samples. Based on the single-pulse photonic curing condition for each film, we project a web speed of 26 m/min, laying a pathway to high-throughput production of perovskite solar modules.


2017 ◽  
Vol 45 ◽  
pp. 302-307 ◽  
Author(s):  
Han Wu ◽  
Chujun Zhang ◽  
Kongxian Ding ◽  
Lijuan Wang ◽  
Yongli Gao ◽  
...  

ChemPlusChem ◽  
2021 ◽  
Author(s):  
Valentino Romano ◽  
Leyla Najafi ◽  
Albertus Adrian Sutanto ◽  
Giorgio Schileo ◽  
Valentin Queloz ◽  
...  

2015 ◽  
Vol 27 (5) ◽  
pp. 1448-1451 ◽  
Author(s):  
Yani Chen ◽  
Yixin Zhao ◽  
Ziqi Liang

2018 ◽  
Vol 6 (34) ◽  
pp. 16347-16354 ◽  
Author(s):  
Meiyue Liu ◽  
Ziming Chen ◽  
Qifan Xue ◽  
Sin Hang Cheung ◽  
Shu Kong So ◽  
...  

Vacuum-assisted thermal annealing not only could improve film morphology and crystallinity, but also could accelerate the sublimation of undesired MACl. With the help of this process, we obtain a highly efficient low-bandgap CH3NH3Sn0.5Pb0.5IxCl3−x perovskite solar cell with a power conversion efficiency of 12.3%.


Solar Energy ◽  
2018 ◽  
Vol 174 ◽  
pp. 218-224 ◽  
Author(s):  
Yaxiao Jiang ◽  
Lin Pan ◽  
Dong Wei ◽  
Wenbiao Li ◽  
Shaohua Li ◽  
...  

ACS Nano ◽  
2015 ◽  
Vol 9 (1) ◽  
pp. 639-646 ◽  
Author(s):  
Feng Xian Xie ◽  
Di Zhang ◽  
Huimin Su ◽  
Xingang Ren ◽  
Kam Sing Wong ◽  
...  

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