Self-Assembled Corn-Husk-Shaped Fullerene Crystals as Excellent Acid Vapor Sensors

Low-molecular-weight acid vapors cause aging and destruction in material processing. In this paper, facile fabrication of novel corn-husk-shaped fullerene C60 crystals (CHFCs) through the dynamic liquid–liquid interfacial precipitation method is reported. The CHFCs were grown at the liquid–liquid interface between isopropyl alcohol (IPA) and a saturated solution of C60 in mesitylene under ambient temperature and pressure conditions. The average length, outer diameter, and inner diameter of CHFCs were ca. 2.88 μm, 672 nm, and 473 nm, respectively. X-ray diffraction (XRD) analysis showed the CHFCs exhibit a mixed face-centered cubic (fcc) and hexagonal-close pack (hcp) crystal phases with lattice parameters a = 1.425 nm, V = 2.899 nm3 for fcc phase and a = 2.182 nm, c = 0.936 nm, a/c ratio = 2.33, and V = 3.859 nm3 for hcp phase. The CHFCs possess mesoporous structure as confirmed by transmission electron microscopy (TEM) and nitrogen sorption analysis. The specific surface area and the pore volume were ca. 57.3 m2 g−1 and 0.149 cm3 g−1, respectively, are higher than the nonporous pristine fullerene C60. Quartz crystal microbalance (QCM) sensing results show the excellent sensing performance CHFCs sensitive to acetic acid vapors due to the enhanced diffusion via mesoporous architecture and hollow structure of the CHFCs, demonstrating the potential of the material for the development of a new sensor system for aliphatic acid vapors sensing.

Capture of Pollutants from Exhaust Gases by Low-Temperature Heating Surfaces

One of the most effective methods towards improving the environmental safety of combustion engines is the application of specially prepared water-fuel emulsions (WFE). The application of WFE makes it possible to reduce primary sulfur fuel consumption and reveals the possibility of capturing the pollutants from exhaust gases by applying condensing low-temperature heating surfaces (LTHS). In order to realize such a double effect, it is necessary to investigate the pollution processes on condensing LTHS of exhaust gas boilers (EGB), especially the process of low-temperature condensing a sulfuric acid vapor from exhaust gases to investigate the influence of condensing LTHS on the intensity of pollutants captured from the exhaust gases. The aim of this research is to assess the influence of the intensity of pollutants captured from exhaust gases by condensing LTHS in dependence of water content in WFE combustion. Investigations were carried out at a special experimental setup. The processing of the results of the experimental studies was carried out using the computer universal statistical graphic system Statgraphics. Results have shown that in the presence of a condensing heating surface, the degree of capture (purification) of pollutants from the exhaust gas flow is up to 0.5–0.6.

Sulfuric acid vapor and sulfur dioxide in the atmosphere of Venus as observed by the Venus Express Radio Science Experiment VeRa

<p>The main cloud deck within Venus' atmosphere, which covers the entire planet between approx. 50 and 70 km altitude, is believed to consist mostly of liquid sulfuric acid. The temperature below the main clouds is high enough to evaporate the H2SO4 droplets into gaseous sulfuric acid forming a haze layer which extends to altitudes as deep as 35 km. Gaseous sulfuric acid in Venus’ lower atmosphere is responsible for a strong absorption of radio waves as seen in Mariner, Pioneer Venus, Magellan and Venera radio science observations. Radio wave absorption measurements can be used to derive the amount of H2SO4 in Venus’ atmosphere. The radio science experiment VeRa onboard Venus Express probed the atmosphere of Venus between 2006 and 2014 with radio signals at 13 cm (S-band) and 3.6 cm (X-band) wavelengths. The orbit of the Venus Express spacecraft allowed to sound the atmosphere over a wide range of latitudes and local times providing a global picture of the sulfuric acid vapor distribution. We present the global H2SO4(g) distribution derived from the X-band radio signal attenuation for the time of the entire Venus Express mission. The observation is compared with results obtained from a 2-D transport model. The VeRa observations were additionally used to estimate the abundance of SO2 near the cloud bottom. The global distribution of SO2 at these altitudes is presented and compared with results obtained from other experiments. Eight years of VEX observation allow to study the long-term evolution of H2SO4 and SO2. The latter is presented for the northern polar region.</p>