Enhancing the Power Output of Direct Carbon Solid Oxide Fuel Cell Using Ba‐Loaded Activated Carbon Fuel

The fuel cell model developed to this research is based on a solid oxide fuel cell (SOFC) integrated with a heat recovery steam generator (HRSG), a gas turbine (GT) and a steam turbine (ST). Three possible technological approaches are compared to suggest the desirable combine cycle. First approach indicates the generation of the required steam in the coupled SOFC and gas turbine cycle. Then the exhaust gas from gas turbine involves driving the HRSG. And the last one involves of using exhaust gases in the HRSG which drives the steam turbine by producing steam for additional power works. To achieve the more efficient conversation of the thermal energy to power output, the component design mainly HRSG and steam turbine have to be made in a great concern. And HRSG is considered as a triple pressure for the taken model. This article is also delineated the analysis of coal fed instead of normal methane gas fed, for the reforming power generation based on thermodynamic processes including CO2 Capture. External reforming in SOFC-HRSG plants fueled by high quality coal enhances efficiency due to improved exhaust heat recovery and higher voltage produced by higher hydrogen partial pressure in the anode inlet. For improving the whole cycle efficiency, power output generation from both SOFC and conventional system (steam turbine and gas turbine) are described as combine system. This model is simulated by the ASPEN plus software which is able to provide thermodynamic and parametric analysis to evaluate the effects of various parameters like air flow rate, temperature, pressure and fuel flow rate on the system performance. Some MATLAB simulations are also added to provide strong opinion for this model through this paper.

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Adsorptive hydrogen chloride and combined hydrogen chloride–hydrogen sulphide removal from biogas for solid oxide fuel cell application

Adsorption Science & Technology ◽

10.1177/0263617418772660 ◽

2018 ◽

Vol 36 (5-6) ◽

pp. 1215-1232 ◽

Cited By ~ 1

Author(s):

Christof Weinlaender ◽

Raphael Neubauer ◽

Martin Hauth ◽

Christoph Hochenauer

Keyword(s):

Activated Carbon ◽

Fuel Cell ◽

Solid Oxide Fuel Cell ◽

Adsorption Capacity ◽

Hydrogen Chloride ◽

Hydrogen Sulphide ◽

Solid Oxide ◽

Fixed Bed Reactor ◽

Oxide Fuel ◽

Experimental Runs

In order to reduce the toxic effect on solid oxide fuel cells performance caused by biogas contaminated with hydrogen chloride and hydrogen sulphide, the purification of biogas is essential. Adsorptive gas purification is a highly auspicious technology to provide pollution-free biogas for solid oxide fuel cell-based power units. In this work the authors examined the influence of different parameters onto the adsorption capacity of three commercially available sorbents. Experimental runs in a laboratory glass downflow fixed-bed reactor were carried out to analyse the adsorption capacity of a potassium carbonate impregnated activated carbon and two sorbents based on a mixture of aluminium oxide and silicon dioxide. Hydrogen chloride removal was accomplished with the impregnated activated carbon and metal oxide-based sorbents. Hydrogen chloride adsorption capacity was analysed under space velocities 8000 and 16,000 h−1. In addition, the effect of a hydrogen chloride inlet concentration of 100 and 1000 ppmv was investigated. Furthermore, pellets in the size of 3–4 mm in diameter were crushed into a fraction between 500 and 1000 µm to investigate the influence of particle size on hydrogen chloride adsorption capacity. Additionally, the combined adsorption of hydrogen chloride and hydrogen sulphide was realized using the impregnated activated carbon. The experimental runs and the results obtained in this work provide useful data for designing an adsorption reactor to clean up biogas and optimizing the process.

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