Infrared Absorption Spectra of Halogenoflavonoids. IV. Absorption Bands between 1400cm−1and 1000cm−1

1963 ◽  
Vol 10 (2-3) ◽  
pp. 125-138 ◽  
Author(s):  
Chi-Hsiung Lin
1995 ◽  
Vol 49 (11) ◽  
pp. 1646-1651 ◽  
Author(s):  
Gow-Weng Peng ◽  
Shou-Kang Chen ◽  
Hok-Shing Liu

The mid-infrared absorption spectra (400–1200 cm−1) of four TiO2-bearing crystalline solids, in the form of rutile (TiO2), Na-titanates (Na2Ti6O13/ Na2Ti3O7), and natisite (Na2TiOSiO4), are presented, providing a clear illustration of their differences in IR band structure (band pattern). Two sharp characteristic peaks of IR absorption bands of natisite have been noted at 725 and 624 cm−1, representing the internal vibration modes of TiO5 (normal) and SiO4 structural units, respectively, and obtainable by comparison with that of Ca-titanosilicate (CaTiOSiO4), NTS glass (Na2O-TiO2-SiO2), and low-cristobalite (SiO2). The tested series of TiO2-bearing crystalline solids has been helpful in presenting a case study in support for the generalization of IR spectra/structure correlations, showing that vibrational spectroscopy can be useful for understanding the crystal chemistry of crystalline solids in terms of the geometric setting of molecular structural units and chemical bonds. It has been qualitatively demonstrated that the Ti-O bond length variations may be broadly correlated with the complexity of IR absorption bands of four TiO2-bearing solids having great diversity in both chemical composition and crystalline structure.


Author(s):  
L Bel'skaya

The comparison of the characteristics of the infrared spectra (height, area of absorption bands) with the biochemical composition was carried out using the example of human saliva. Correlations of both individual absorption bands and their combinations with a number of biochemical parameters of saliva have been established. The substantiation of the revealed regularities based on the metabolic characteristics of this biological fluid is proposed.


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