Electrochemical oxidation of the pesticide nitenpyram using a Gd‐PbO 2 anode: operation parameter optimization and degradation mechanism

2020 ◽  
Vol 95 (8) ◽  
pp. 2120-2128 ◽  
Author(s):  
Yang Yang ◽  
Yun Xia ◽  
Feng Wei ◽  
Liman Zhang ◽  
Yingwu Yao

2015 ◽  
Vol 32 (8) ◽  
pp. 1570-1577 ◽  
Author(s):  
Ali Reza Rahmani ◽  
Davood Nematollahi ◽  
Ghasem Azarian ◽  
Kazem Godini ◽  
Zohreh Berizi


Chemosphere ◽  
2018 ◽  
Vol 193 ◽  
pp. 89-99 ◽  
Author(s):  
Yapeng He ◽  
Xue Wang ◽  
Weimin Huang ◽  
Rongling Chen ◽  
Wenli Zhang ◽  
...  


2014 ◽  
Vol 245 ◽  
pp. 359-366 ◽  
Author(s):  
Qizhou Dai ◽  
Yijing Xia ◽  
Chen Sun ◽  
Mili Weng ◽  
Jun Chen ◽  
...  


2013 ◽  
Vol 67 (10) ◽  
pp. 2177-2183 ◽  
Author(s):  
Weijing Liu ◽  
Yong Chen ◽  
Hongyi Li ◽  
Qin Zhong

Electrochemical degradation of 2,5-dichloro-1,4-phenylenediamine (DP) in aqueous solution by anodic oxidation was investigated. Linear sweep voltammograms and cyclic voltammograms were studied. The influence of operating parameters on electrochemical oxidation of DP was studied as a function of the current density, initial pH, and initial concentration of DP. The degradation kinetics analysis indicated that the electrochemical degradation of DP followed a first-order reaction. The degradation intermediates during electrochemical oxidation were analyzed by UV–vis spectrophotometer, ionic chromatograph (IC), and gas chromatography/mass spectrometry (GC/MS). The combustion efficiency of DP at the anode was also estimated. The electrochemical oxidation of DP resulted in the release of NH4+ and Cl−. Based on these results, a degradation mechanism for electrochemical degradation of DP by anodic oxidation was proposed.



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