Instrumental Methods for Cage Occupancy Estimation of Gas Hydrate

Studies revealed that gas hydrate cages, especially small cages, are incompletely filled with guest gas molecules, primarily associated with pressure and gas composition. The ratio of hydrate cages occupied by guest molecules, defined as cage occupancy, is a critical parameter to estimate the resource amount of a natural gas hydrate reservoir and evaluate the storage capacity of methane or hydrogen hydrate as an energy storage medium and carbon dioxide hydrate as a carbon sequestration matrix. As the result, methods have been developed to investigate the cage occupancy of gas hydrate. In this review, several instrument methods widely applied for gas hydrate analysis are introduced, including Raman, NMR, XRD, neutron diffraction, and the approaches to estimate cage occupancy are summarized.

Characterization of Thin Gas Hydrate Reservoir in Ulleung Basin with Stepwise Seismic Inversion

Natural gas hydrates (GHs) filling sand layer pores are the most promising GHs that can be produced via conventional mechanisms in deep-sea environments. However, the seismic tracking of such thin GH-bearing sand layers is subject to certain limitations. For example, because most GH-bearing sand layers are thin and sparsely interbedded with mud layers, conventional seismic data with a maximum resolution of ~10 m are of limited use for describing their spatial distribution. The 2010 Ulleung Basin drilling expedition identified a relatively good GH reservoir at the UBGH2-6 site. However, the individual GH-bearing sand layers at this site are thin and cannot therefore be reliably tracked using conventional seismic techniques. This study presents a new thin layer tracking method using stepwise seismic inversion and 3D seismic datasets with two different resolutions. The high-resolution acoustic impedance volume obtained is then used to trace thin layers that cannot be harnessed with conventional methods. Moreover, we estimate the high-resolution regional GH distribution based on GH saturation derived from acoustic impedance at UBGH2-6. The thin GH layers, previously viewed as a single layer because of limited resolution, are further subdivided, traced, and characterized in terms of lateral variation.

Gas Hydrate System Offshore Chile

In recent decades, the Chilean margin has been extensively investigated to better characterize the complex geological setting through the geophysical data. The analysis of seismic lines allowed us to identify the occurrence of gas hydrates and free gas in many places along the margin and the change of the pore fluid due to the potential hydrate dissociation. The porosity reduction due to the hydrate presence is linked to the slope to identify the area more sensitive in case of natural phenomena or induced by human activities that could determine gas hydrate dissociations and/or leakage of the free gas trapped below the gas-hydrate stability zone. Clearly, the gas hydrate reservoir could be a strategic energy reserve for Chile. The steady-state modelling pointed out that the climate change could determine gas hydrate dissociation, triggering slope failure. This hypothesis is supported by the presence of high concentrations of gas hydrate in correspondence of important seafloor slope. The dissociation of gas hydrate could change the petrophysical characteristics of the subsoil triggering slopes, which already occurred in the past. Consequently, it is required to improve knowledge about the behavior of the gas hydrate system in a function of complex natural phenomena before the exploitation of this important resource.