Enhancing the Colloidal Stability and Electrical Conductivity of Single-Walled Carbon Nanotubes Dispersed in Water

2015 ◽  
Vol 217 (5) ◽  
pp. 683-700 ◽  
Author(s):  
Rinky D. Devre ◽  
Bridgette M. Budhlall ◽  
Carol F. Barry
Nanomaterials ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 1113 ◽  
Author(s):  
Bogumiła Kumanek ◽  
Tomasz Wasiak ◽  
Grzegorz Stando ◽  
Paweł Stando ◽  
Dariusz Łukowiec ◽  
...  

Despite the widespread use of sonication for individualization of nanomaterials, its destructive nature is rarely acknowledged. In this study, we demonstrated how exposure of the material to a hostile sound wave environment can be limited by the application of another preprocessing step. Single-walled carbon nanotubes (CNTs) were initially ground in a household coffee grinder, which enabled facile deagglomeration thereof. Such a simple approach enabled us to obtain high-quality CNT dispersion at reduced sonication time. Most importantly, electrical conductivity of free-standing films prepared from these dispersion was improved almost fourfold as compared with unground material eventually reaching 1067 ± 34 S/cm. This work presents a new approach as to how electrical properties of nanocarbon ensembles may be enhanced without the application of doping agents, the presence of which is often ephemeral.


2011 ◽  
Vol 306-307 ◽  
pp. 1182-1185
Author(s):  
Hong Mei Niu

Nanocomposites of single-walled carbon nanotubes modified polypyrrole (PPy/SWNTs) were synthesized successfully by in situ oxidative polymerization method in the FeCl3·6H2O solution. The morphological structure, electrical conductivity and thermal stability of the nanocomposites were characterized by TEM, SEM, FTIR and TGA. The PPy/SWNTs were 50-100 nm in diameter of PPy coating uniformly on the surface of the SWNTs. FTIR spectra revealed the presence of covalently interaction between the PPy and the carbon nanotubes. The electrical conductivity of PPy/SWNTs composite and pure PPy were 93 and 8.0×10-3 S/cm, respectively. Meanwhile, the PPy/SWNTs composites possessed higher thermal stability (65.9 wt. % weight loss at 600 °C) compared to pure PPy (81.2 wt. % weight loss at 600°C), the content of SWNTs was 15.3 wt. %.


2008 ◽  
Vol 20 (9) ◽  
pp. 3120-3126 ◽  
Author(s):  
Maxim N. Tchoul ◽  
Warren T. Ford ◽  
Mai L. P. Ha ◽  
Israel Chavez-Sumarriva ◽  
Brian P. Grady ◽  
...  

2019 ◽  
Vol 27 (03) ◽  
pp. 1950123 ◽  
Author(s):  
MOHAMMAD R. MOHAMMAD ◽  
DUHA S. AHMED ◽  
MUSTAFA K. A. MOHAMMED

Raw single-walled carbon nanotubes (SWCNTs) were oxidized by using sulfuric acid and nitric acid at 3:1 ratio to produce oxygen functional groups attached to SWCNTs surfaces. Then, the oxidized SWCNTs are coated with zinc oxide and silver nanoparticles by chemical precipitation route to synthesize ZnO/Ag-SWCNTs nanocomposite material. The nanocomposite sample was analyzed via zeta potential analyzer, ultraviolet-visible (UV-Vis) spectrophotometer, field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and Raman spectroscopy to investigate colloidal stability, optical, morphological, and structural properties. The SWCNT properties were found to be changed after the addition of ZnO/Ag nanoparticles. Hence, the new ZnO/Ag-SWCNTs nanocomposite is a good candidate for photocatalyst applications and biological applications.


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