Low percolation threshold and high electrical conductivity in melt-blended polycarbonate/multiwall carbon nanotube nanocomposites in the presence of poly(ε-caprolactone)

2013 ◽  
Vol 54 (3) ◽  
pp. 646-659 ◽  
Author(s):  
Sandip Maiti ◽  
Supratim Suin ◽  
Nilesh K. Shrivastava ◽  
B.B. Khatua
2011 ◽  
Vol 239-242 ◽  
pp. 145-149 ◽  
Author(s):  
Hsin Chih Peng ◽  
Chen Feng Kuan ◽  
Chia Hsun Chen ◽  
Kun Chang Lin ◽  
Hsu Chiang Kuan

The preparation of multi-walled carbon nanotube/polylactide (PLA)/Ecoflex® biodegradable composites is described. Three modifiers, maleic anhydride ,methyl methacrylate and vinyltrimethoxysilane , were utilized to modify multiwall carbon nanotube. The dispersion of multi-walled carbon nanotube was enhanced by covalent or hydrogen bonding between modified multi-walled carbon and biodegradable blend. The tensile strengths of pristine PLA/Ecoflex® resin and 4 wt% modified multi-walled carbon composites are 68 kgf/cm2 and 257 kgf/cm2, respectively (representing a difference of 380%). High electrical conductivity can be achieved at a low carbon nanotube loading. When 1wt% modified multi-walled carbon was added to PLA/Ecoflex® matrix, the surface resistance of the composite fell from 1.46×1016 to 7.88 × 102 Ω/Υ (by 1013 order).


2013 ◽  
Vol 737 ◽  
pp. 183-190 ◽  
Author(s):  
Anne Zulfia ◽  
Sutopo ◽  
Bangkit Indriyana ◽  
M.E. Albar ◽  
S. Rohman

Polypropylene can be improved an electrical conductivity by addition of carbon and multiwall carbon nanotube (MWCNT) as well as combination with copper (Cu) powder. Multiwall carbon nanotube used from 0.1 wt%, 0.5 wt% to 1 wt% while the addition of Cu powder into PP/C was various from 0.1 wt%, 0.2wt% to 0.5wt% respectively. This research focuses on material design of composite based on polymer and carbon to improve an electrical conductivity according to electrical conductivity requirement for bipolar plate. Bipolar plate is one of the components in PEMFC constituted a crucial component that collects and transfers electron from the anode to the cathode, therefore it should possess high electrical conductivity. The main discussion in this research is to analyze the role of multiwall carbon nano tube (MWCNT) and copper on electrical conductivity of polymer composites produced. Functional groups analysis using Fourier Transform Infrared Spectroscopy (FTIR) was also carried out to investigate whether carbon has been mixed perfectly within polypropylene. It is found that the effect of adding a small amount of MWCNT and Cu have improved their electrical conductivity of composites up to 15.62 S/cm.


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