Physical properties and structure of silk. V. Thermal behavior of silk fibroin in the random-coil conformation

1977 ◽  
Vol 15 (9) ◽  
pp. 1675-1683 ◽  
Author(s):  
Jun Magoshi ◽  
Yoshiko Magoshi ◽  
Shigeo Nakamura ◽  
Nobutami Kasai ◽  
Masao Kakudo
2021 ◽  
Author(s):  
Joong Tark Han ◽  
Joon Young Cho ◽  
Jeong Hoon Kim

The thermal stability of solution-exfoliated graphene oxide (GO) in air is one of the most important physical properties influencing its potential applications. To date, majority of the GO prepared by...


2013 ◽  
Vol 721 ◽  
pp. 274-277
Author(s):  
Li Li Ji ◽  
Qiao Ling Li ◽  
Zeng Hu Yang ◽  
Wei Jing Hu ◽  
Kui Hua Zhang

Vitamin E d-alpha-tocopheryl polyethylene glycol 1000 succinate (VE TPGS) loaded silk fibroin (SF)/ hyaluronic acid (HA) nanofibrous scaffolds were fabricated by means of electrospinning to biomimic the natural extracellular matrix. Scanning electronic microscopy (SEM) results indicated that electrospun VE TPGS loaded SF/HA nanofibers were ribbon-shaped, the width of nanofibers decreased slightly with the addition of VE TPGS to SF/HA blended solutions. Fourier transform infrared (FTIR) spectroscopy and Wide-angle X-ray diffraction (WAXD) curves revealed that VE TPGS did not induce SF conformation from random coil to β-sheet. SF conformation converted from random coil to β-sheet after being treated with 75% ethanol vapor. In vitro release studies confirmed VE TPGS had no obvious burst release and present good release behavior.


2011 ◽  
Vol 51 (2) ◽  
pp. 775-779 ◽  
Author(s):  
Maria Lúcia Pereira Antunes ◽  
Sara Jane Couperthwaite ◽  
Fabiano Tomazini da Conceição ◽  
Carolina Petrisin Costa de Jesus ◽  
Pedro Kunihiko Kiyohara ◽  
...  

2011 ◽  
Vol 175-176 ◽  
pp. 176-180
Author(s):  
Hui Ying Wu ◽  
Bao Qi Zuo

Silk fibroin modified viscose fiber (SFVF) was a new fiber with silken handling and luster, which was produced via adding silk fibroin (SF) during the viscose process. In this paper, a series of testing had been done to study the structure and properties of SFVF. The amino acid content of SFVF was measured by HITACHI-835-50 amino acid tester. The morphology, structure, thermal and mechanical property of SFVF were characterized by SEM, FTIR, DSC and electronic strength tester. The results indicated that SFVF consisted of many kinds of amino acids compared with pure viscose fiber (VF) yarn. The results of SEM showed more continuous multi fine slots existed in the longitudinal section of SFVF than in that of VF, demonstrating that wet permeability and vapor transmission could be enhanced for the SFVF to certain extent. Results from FTIR indicated that the secondary structure of SFVF was mainly β-sheet and random coil, and its absorption peaks were 1616cm-1 and 1644 cm-1 respectively. The DSC curve shown the thermal decomposition temperature of SFVF was about 328.39°C, which was close to that of VF. It suggested that the SF modification had no obvious influence on thermal stability of VF. At last, the dry-strength and wet-strength of SFVF was close to that of VF. Therefore, the application of VF would be expanded with the SF modification.


RSC Advances ◽  
2015 ◽  
Vol 5 (119) ◽  
pp. 98553-98558 ◽  
Author(s):  
Chen Liu ◽  
Jiaqi Sun ◽  
Min Shao ◽  
Bin Yang

Centrifugal spinning converts the conformation of silk fibroin from random coil to β-sheet more easily than electrospinning, which results in fiber differences on secondary structures, orientation and thermal properties.


2006 ◽  
Vol 44 (23) ◽  
pp. 3418-3426 ◽  
Author(s):  
Majibur Rahman Khan ◽  
Yasuo Gotoh ◽  
Mikihiko Miura ◽  
Hideaki Morikawa ◽  
Masanobu Nagura

2014 ◽  
Vol 198 ◽  
pp. 354-357 ◽  
Author(s):  
Alina Sionkowska ◽  
Katarzyna Lewandowska ◽  
Anna Płanecka

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