Synthesis of amphiphilic copolymer brushes possessing alternating poly(methyl methacrylate) and poly(N -isopropylacrylamide) grafts via a combination of ATRP and click chemistry

2009 ◽  
Vol 47 (10) ◽  
pp. 2608-2619 ◽  
Author(s):  
Jun Yin ◽  
Zhishen Ge ◽  
Hao Liu ◽  
Shiyong Liu
2011 ◽  
Vol 32 (6) ◽  
pp. 869-881 ◽  
Author(s):  
Şaziye Uğur ◽  
Önder Yargı ◽  
Yasemin Yüksel Durmaz ◽  
Bünyamin Karagöz ◽  
Niyazi Bıçak ◽  
...  

2012 ◽  
Vol 714 ◽  
pp. 291-295 ◽  
Author(s):  
Błażej Włodarczyk ◽  
Joanna Pietrasik ◽  
Marian Zaborski

The synthesis of polymer brushes containing poly (methyl methacrylate) (PMMA) chains grafted from hydroxyapatite (HAP) particles was disscussed. Surface of commercially available hydroxyapatite was first modified with atom transfer radical polymerization (ATRP) initiator and hydrophobized with isobutyric acid, and then surface-initiated ATRP was conducted. Properties of obtained hybrids were studied by dynamic light scattering (DLS) and gel permeation chromatography (GPC). Polymers with various molecular weight up toMn=96,100 g/mol were obtained with good control;Mw/Mn<1.2. Copolymer brushes of poly (methyl methacrylate-stat-benzophenone methacrylate) (P(MMA-stat-BPMA) were also synthesized and cross-linking ability of such materials under UV radiation was confirmed.


2013 ◽  
Vol 214 (17) ◽  
pp. 1990-1997 ◽  
Author(s):  
Carmine Capacchione ◽  
Antonella De Roma ◽  
Antonio Buonerba ◽  
Vito Speranza ◽  
Stefano Milione ◽  
...  

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