Effects of annealing above T g on the physical aging of quenched PLLA studied by modulated temperature FTIR

2018 ◽  
Vol 57 (3) ◽  
pp. 174-181 ◽  
Author(s):  
Valerio Di Lisio ◽  
Elisa Sturabotti ◽  
Iolanda Francolini ◽  
Antonella Piozzi ◽  
Andrea Martinelli



Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 954
Author(s):  
Xavier Monnier ◽  
Sara Marina ◽  
Xabier Lopez de Pariza ◽  
Haritz Sardón ◽  
Jaime Martin ◽  
...  

The present work aims to provide insights on recent findings indicating the presence of multiple equilibration mechanisms in physical aging of glasses. To this aim, we have investigated a glass forming polyether, poly(1-4 cyclohexane di-methanol) (PCDM), by following the evolution of the enthalpic state during physical aging by fast scanning calorimetry (FSC). The main results of our study indicate that physical aging persists at temperatures way below the glass transition temperature and, in a narrow temperature range, is characterized by a two steps evolution of the enthalpic state. Altogether, our results indicate that the simple old-standing view of physical aging as triggered by the α relaxation does not hold true when aging is carried out deep in the glassy state.



2019 ◽  
Vol 28 (6) ◽  
pp. 1900036
Author(s):  
Georgios Grigorios Vogiatzis ◽  
Lambèrt Cécile Angelo van Breemen ◽  
Markus Hütter


Polymer ◽  
2021 ◽  
Vol 217 ◽  
pp. 123447
Author(s):  
N. Belov ◽  
D. Nikolaeva ◽  
Yu Yampolskii


1999 ◽  
Vol 15 (1) ◽  
pp. 37-46 ◽  
Author(s):  
J. R. Gillmor ◽  
J. Greenert


Polymer ◽  
2006 ◽  
Vol 47 (9) ◽  
pp. 3104-3111 ◽  
Author(s):  
J.H. Kim ◽  
W.J. Koros ◽  
D.R. Paul


1996 ◽  
Vol 29 (10) ◽  
pp. 3470-3474 ◽  
Author(s):  
C. Y. Stacey Fu ◽  
Hilary S. Lackritz ◽  
Duane B. Priddy, ◽  
James E. McGrath


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