scholarly journals Electric Field Induced Biomimetic Transmembrane Electron Transport Using Carbon Nanotube Porins (Small 32/2021)

Small ◽  
2021 ◽  
Vol 17 (32) ◽  
pp. 2170164
Author(s):  
Jacqueline M. Hicks ◽  
Yun‐Chiao Yao ◽  
Sydney Barber ◽  
Nigel Neate ◽  
Julie A. Watts ◽  
...  
Small ◽  
2021 ◽  
pp. 2102517
Author(s):  
Jacqueline M. Hicks ◽  
Yun‐Chiao Yao ◽  
Sydney Barber ◽  
Nigel Neate ◽  
Julie A. Watts ◽  
...  

2021 ◽  
Author(s):  
Jacqueline M. Hicks ◽  
Yun-Chiao Yao ◽  
Sydney Barber ◽  
Aleksandr Noy ◽  
Nigel Neate ◽  
...  

<p>Cells modulate their homeostasis through the control of redox reactions via transmembrane electron transport systems. These are largely mediated via oxidoreductase enzymes. Their use in biology has been linked to a host of systems including reprogramming for energy requirements in cancer. Consequently, our ability to modulate membrane redox systems may give rise to opportunities to modulate underlying biology. The current work aimed to develop a wireless bipolar electrochemical approach to form on-demand electron transfer across biological membranes. To achieve this goal, we show that using membrane inserted carbon nanotube porins that can act as bipolar nanoelectrodes, we could control electron flow with externally applied electric fields across membranes. Before this work, bipolar electrochemistry has been thought to require high applied voltages not compatible with biological systems. We show that bipolar electrochemical reaction via gold reduction at the nanotubes could be modulated at low cell-friendly voltages, providing an opportunity to use bipolar electrodes to control electron flux across membranes. Our observations present a new opportunity to use bipolar electrodes to alter cell behavior via wireless control of membrane electron transfer.</p>


2021 ◽  
Author(s):  
Jacqueline M. Hicks ◽  
Yun-Chiao Yao ◽  
Sydney Barber ◽  
Nigel Neate ◽  
Julie Watts ◽  
...  

<p>Cells modulate their homeostasis through the control of redox reactions via transmembrane electron transport systems. These are largely mediated via oxidoreductase enzymes. Their use in biology has been linked to a host of systems including reprogramming for energy requirements in cancer. Consequently, our ability to modulate membrane redox systems may give rise to opportunities to modulate underlying biology. The current work aimed to develop a wireless bipolar electrochemical approach to form on-demand electron transfer across biological membranes. To achieve this goal, we show that using membrane inserted carbon nanotube porins that can act as bipolar nanoelectrodes, we could control electron flow with externally applied electric fields across membranes. Before this work, bipolar electrochemistry has been thought to require high applied voltages not compatible with biological systems. We show that bipolar electrochemical reaction via gold reduction at the nanotubes could be modulated at low cell-friendly voltages, providing an opportunity to use bipolar electrodes to control electron flux across membranes. Our observations present a new opportunity to use bipolar electrodes to alter cell behavior via wireless control of membrane electron transfer.</p>


2021 ◽  
Author(s):  
Jacqueline M. Hicks ◽  
Yun-Chiao Yao ◽  
Sydney Barber ◽  
Nigel Neate ◽  
Julie Watts ◽  
...  

<p>Cells modulate their homeostasis through the control of redox reactions via transmembrane electron transport systems. These are largely mediated via oxidoreductase enzymes. Their use in biology has been linked to a host of systems including reprogramming for energy requirements in cancer. Consequently, our ability to modulate membrane redox systems may give rise to opportunities to modulate underlying biology. The current work aimed to develop a wireless bipolar electrochemical approach to form on-demand electron transfer across biological membranes. To achieve this goal, we show that using membrane inserted carbon nanotube porins that can act as bipolar nanoelectrodes, we could control electron flow with externally applied electric fields across membranes. Before this work, bipolar electrochemistry has been thought to require high applied voltages not compatible with biological systems. We show that bipolar electrochemical reaction via gold reduction at the nanotubes could be modulated at low cell-friendly voltages, providing an opportunity to use bipolar electrodes to control electron flux across membranes. Our observations present a new opportunity to use bipolar electrodes to alter cell behavior via wireless control of membrane electron transfer.</p>


Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1810
Author(s):  
Mengjie Li ◽  
Qilong Wang ◽  
Ji Xu ◽  
Jian Zhang ◽  
Zhiyang Qi ◽  
...  

Due to the high field enhancement factor and photon-absorption efficiency, carbon nanotubes (CNTs) have been widely used in optically induced field-emission as a cathode. Here, we report vertical carbon nanotube arrays (VCNTAs) that performed as high-density electron sources. A combination of high applied electric field and laser illumination made it possible to modulate the emission with laser pulses. When the bias electric field and laser power density increased, the emission process is sensitive to a power law of the laser intensity, which supports the emission mechanism of optically induced field emission followed by over-the-barrier emission. Furthermore, we determine a polarization dependence that exhibits a cosine behavior, which verifies the high possibility of optically induced field emission.


2015 ◽  
Vol 117 (21) ◽  
pp. 214306 ◽  
Author(s):  
Richard J. Castellano ◽  
Cevat Akin ◽  
Gabriel Giraldo ◽  
Sangil Kim ◽  
Francesco Fornasiero ◽  
...  

2001 ◽  
Vol 79 (2) ◽  
pp. 260-262 ◽  
Author(s):  
G. W. Ho ◽  
A. T. S. Wee ◽  
J. Lin

2017 ◽  
Vol 19 (32) ◽  
pp. 21507-21513 ◽  
Author(s):  
Hong-Li Zeng ◽  
Yan-Dong Guo ◽  
Xiao-Hong Yan ◽  
Jie Zhou

The spin-Seebeck effect (SSE) in linearly hydrogenated carbon nanotubes (CNTs) is realized, where partial hydrogenation makes CNTs acquire magnetism. Moreover, an odd–even effect of the SSE is observed, and the even cases could be used as spin-Seebeck diodes, without the need for an electric field or gate voltage.


Sign in / Sign up

Export Citation Format

Share Document