Metal–Organic Frameworks‐Derived Nitrogen‐Doped Porous Carbon Nanocubes with Embedded Co Nanoparticles as Efficient Sulfur Immobilizers for Room Temperature Sodium–Sulfur Batteries

Small Methods ◽  
2021 ◽  
pp. 2100455
Author(s):  
Jirong Mou ◽  
Yijuan Li ◽  
Ting Liu ◽  
Wenjia Zhang ◽  
Mei Li ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Room Temperature ◽  
Metal Organic Frameworks ◽  
Nitrogen Doped ◽  
Metal Organic ◽  
Co Nanoparticles ◽  
Sodium Sulfur

scholarly journals Nickel sulfide nanocrystals on nitrogen-doped porous carbon nanotubes with high-efficiency electrocatalysis for room-temperature sodium-sulfur batteries

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Zichao Yan ◽  
Jin Xiao ◽  
Weihong Lai ◽  
Li Wang ◽  
Florian Gebert ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Porous Carbon ◽  
Density Functional ◽  
Room Temperature ◽  
Lewis Base ◽  
Nitrogen Doped ◽  
High Electronic Conductivity ◽  
Sulfur Host ◽  
Sodium Sulfur ◽  
Sulfur Cathodes

Abstract Polysulfide dissolution and slow electrochemical kinetics of conversion reactions lead to low utilization of sulfur cathodes that inhibits further development of room-temperature sodium-sulfur batteries. Here we report a multifunctional sulfur host, NiS2 nanocrystals implanted in nitrogen-doped porous carbon nanotubes, which is rationally designed to achieve high polysulfide immobilization and conversion. Attributable to the synergetic effect of physical confinement and chemical bonding, the high electronic conductivity of the matrix, closed porous structure, and polarized additives of the multifunctional sulfur host effectively immobilize polysulfides. Significantly, the electrocatalytic behaviors of the Lewis base matrix and the NiS2 component are clearly evidenced by operando synchrotron X-ray diffraction and density functional theory with strong adsorption of polysulfides and high conversion of soluble polysulfides into insoluble Na2S2/Na2S. Thus, the as-obtained sulfur cathodes exhibit excellent performance in room-temperature Na/S batteries.

Metal-Organic Frameworks (MOFs)-Derived Nitrogen-Doped Porous Carbon Anchored on Graphene with Multifunctional Effects for Lithium-Sulfur Batteries

2018 ◽  
Vol 28 (38) ◽  
pp. 1707592 ◽  
Author(s):  
Ke Chen ◽  
Zhenhua Sun ◽  
Ruopian Fang ◽  
Ying Shi ◽  
Hui-Ming Cheng ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Nitrogen Doped ◽  
Lithium Sulfur Batteries ◽  
Metal Organic ◽  
Lithium Sulfur

A nitrogen doped carbonized metal–organic framework for high stability room temperature sodium–sulfur batteries

2016 ◽  
Vol 4 (32) ◽  
pp. 12471-12478 ◽  
Author(s):  
Yu-Ming Chen ◽  
Wenfeng Liang ◽  
Si Li ◽  
Feng Zou ◽  
Sarang M. Bhaway ◽  
...  
Keyword(s):  
High Stability ◽  
Room Temperature ◽  
Composite Electrode ◽  
Metal Organic Framework ◽  
Specific Capacity ◽  
Nitrogen Doped ◽  
Metal Organic ◽  
Sodium Sulfur ◽  
Organic Framework

A nitrogen-doped carbonized metal–organic framework was utilized for room temperature sodium sulfur batteries. The cZIF-8/S composite electrode exhibited good cyclability over 250 cycles at 0.2C with a specific capacity of 500 mA h g−1.

NiPt–MnOx supported on N-doped porous carbon derived from metal–organic frameworks for highly efficient hydrogen generation from hydrazine

2016 ◽  
Vol 4 (15) ◽  
pp. 5616-5622 ◽  
Author(s):  
Bingquan Xia ◽  
Teng Liu ◽  
Wei Luo ◽  
Gongzhen Cheng
Keyword(s):  
Catalytic Activity ◽  
Porous Carbon ◽  
Hydrogen Generation ◽  
Metal Organic Frameworks ◽  
Porous Carbons ◽  
Nitrogen Doped ◽  
Highly Efficient ◽  
Different Temperatures ◽  
Metal Organic

Nitrogen-doped porous carbons derived from ZIF-7 annealing at different temperatures have been synthesized and used as support matrices to anchor NiPt alloy and MnOx NPs. The resulting (Ni3Pt7)0.5–(MnOx)0.5/NPC-900 exhibits superior catalytic activity with TOF values of 706 and 120 h−1 at 323 K and 298 K respectively, higher than most reported values.

Highly dispersed Co-based Fischer–Tropsch synthesis catalysts from metal–organic frameworks

2017 ◽  
Vol 5 (17) ◽  
pp. 8081-8086 ◽  
Author(s):  
Bin Qiu ◽  
Ce Yang ◽  
Wenhan Guo ◽  
Yao Xu ◽  
Zibin Liang ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Tropsch Synthesis ◽  
Fischer Tropsch ◽  
Fischer Tropsch Synthesis ◽  
Highly Dispersed ◽  
Metal Organic ◽  
Synthesis Catalysts ◽  
Co Nanoparticles

Ultra-small Co nanoparticles embedded in hierarchically porous carbon were made in situ from metal–organic frameworks and used as catalysts in the Fischer–Tropsch synthesis.

Nitrogen-doped graphitic hierarchically porous carbon nanofibers obtained via bimetallic-coordination organic framework modification and their application in supercapacitors

2018 ◽  
Vol 47 (21) ◽  
pp. 7316-7326 ◽  
Author(s):  
Yuechao Yao ◽  
Peng Liu ◽  
Xiaoyan Li ◽  
Shaozhong Zeng ◽  
Tongbin Lan ◽  
...  
Keyword(s):  
Carbon Nanofibers ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Hierarchically Porous ◽  
Nitrogen Doped ◽  
Metal Organic ◽  
Acid Wash ◽  
Organic Framework

Herein, N-doped graphitic hierarchically porous carbon nanofibers (NGHPCF) were prepared by electrospinning the composite of bimetallic-coordination metal–organic frameworks and polyacrylonitrile, followed by a pyrolysis and acid wash process.

Design of pomegranate-like clusters with NiS2 nanoparticles anchored on nitrogen-doped porous carbon for improved sodium ion storage performance

2018 ◽  
Vol 6 (15) ◽  
pp. 6595-6605 ◽  
Author(s):  
Jiabao Li ◽  
Jinliang Li ◽  
Dong Yan ◽  
Shujin Hou ◽  
Xingtao Xu ◽  
...  
Keyword(s):  
Porous Carbon ◽  
Anode Materials ◽  
Metal Organic Frameworks ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Nitrogen Doped ◽  
Storage Performance ◽  
Ion Storage ◽  
Metal Organic ◽  
Sodium Ion Storage

Pomegranate-like NiS2/nitrogen-doped porous carbon hybrids were prepared from metal–organic frameworks and applied as anode materials for sodium-ion batteries.

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