Site and Enantioselective Aliphatic C−H Oxidation with Bioinspired Chiral Complexes

A series of chiral complexes of the form Ir(NHC)2(aa)(H)(X) (NHC = N-heterocyclic carbene, aa = chelated amino acid, X = halide) was synthesized by oxidative addition of -amino acids to iridium(I) bis-NHC compounds and screened for asymmetric transfer hydrogenation of ketones. Following optimization of the reaction conditions, NHC, and amino acid ligands, high enantioselectivity was achieved when employing the Ir(IMe)2(l-Pro)(H)(I) catalyst (IMe = 1,3-dimethylimidazol-2-ylidene), which asymmetrically reduces a range of acetophenone derivatives in up to 95% enantiomeric excess.

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ChemInform Abstract: A THEORY OF THE CIRCULAR DICHROISM OF THE D-D TRANSITIONS OF CHIRAL COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.197825049 ◽

1978 ◽

Vol 9 (25) ◽

Author(s):

P. E. SCHIPPER

Keyword(s):

Circular Dichroism ◽

Chiral Complexes ◽

Circular Dichroïsm

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ChemInform Abstract: ASYMMETRIC CATALYSIS WITH CHIRAL COMPLEXES OF RHODIUM-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE. 6. ON THE MECHANISM OF REDUCTION OF (E,Z)-α-ACYLAMINOCINNAMIC ACIDS WITH HOMOGENEOUS RHODIUM CATALYSTS

Chemischer Informationsdienst ◽

10.1002/chin.197909091 ◽

1979 ◽

Vol 10 (9) ◽

Author(s):

C. DETELLIER ◽

G. GELBARD ◽

H. B. KAGAN

Keyword(s):

Asymmetric Catalysis ◽

Rhodium Catalysts ◽

Chiral Complexes

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Synthesis and Fluxional Behavior, Including a Comparative Analysis of the Pd−N Bond Rupture, of New Chiral Complexes of Palladium(0) and -(II) with a Rigid (Aminoferrocenyl)phosphine Ligand. Crystal Structure of the Two Rotamers of a Palladium(0) Maleic Anhydride Complex.

Organometallics ◽

10.1021/om9808458 ◽

1998 ◽

Vol 17 (26) ◽

pp. 5941-5941 ◽

Cited By ~ 2

Author(s):

Felipe Gómez-de la Torre ◽

Félix A. Jalón ◽

Ana López-Agenjo ◽

Blanca R. Manzano ◽

Ana Rodríguez ◽

...

Keyword(s):

Crystal Structure ◽

Comparative Analysis ◽

Maleic Anhydride ◽

Phosphine Ligand ◽

Bond Rupture ◽

Chiral Complexes

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Asymmetric epoxidation of alkenes with aqueous t-BuOOH catalyzed by novel chiral complexes of chromium(III) containing tridentate Schiff-base ligands

Journal of Molecular Catalysis A Chemical ◽

10.1016/j.molcata.2007.03.011 ◽

2007 ◽

Vol 271 (1-2) ◽

pp. 270-276 ◽

Cited By ~ 11

Author(s):

Debabrata Chatterjee ◽

Susan Basak ◽

Jacques Muzart

Keyword(s):

Schiff Base ◽

Asymmetric Epoxidation ◽

Schiff Base Ligands ◽

Chiral Complexes ◽

Epoxidation Of Alkenes ◽

Tridentate Schiff Base

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Access to luminescent mesophases of gold(I) chiral complexes by thermal or mechanic stimuli. The role of the tertiary carbon

Journal of Materials Chemistry C ◽

10.1039/d1tc04325k ◽

2022 ◽

Author(s):

Maria Barcenilla Castellano ◽

Cesar Folcia ◽

Josu Ortega ◽

Jesus Etxebarria ◽

Silverio Coco ◽

...

Keyword(s):

Thermal Stress ◽

Chiral Complexes ◽

Tertiary Carbon

Chiral gold(I) isocyanide complexes [Au(p-C6F4OR1)(p-CNC6H4(O2CC6H4(OR2)] with R1, R2 or both being (R)-2-octyl, display an interesting and unprecedented response to mechanical or thermal stress. For all the complexes, heating leads to...

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