Standardless analysis of small amounts of mineral samples by SR-XRF and conventional XRF analyses

2002 ◽  
Vol 31 (6) ◽  
pp. 419-423 ◽  
Author(s):  
J. D'Angelo ◽  
E. Perino ◽  
E. Marchevsky ◽  
J. A. Riveros
Keyword(s):  
Sr Xrf ◽  
Standardless Analysis ◽  
Xrf Analyses

Precision and bias in quantitative EDS: ASTM results

1992 ◽  
Vol 50 (2) ◽  
pp. 1654-1655
Author(s):  
John J. Friel
Keyword(s):  
Stainless Steel ◽  
Quantitative Analysis ◽  
Mechanical Alloy ◽  
Dead Time ◽  
Test Program ◽  
Round Robin Test ◽  
Wide Range ◽  
American Society ◽  
Takeoff Angle ◽  
Standardless Analysis

Committee E-04 on Metallography of the American Society for Testing and Materials (ASTM) conducted an interlaboratory round robin test program on quantitative energy dispersive spectroscopy (EDS). The test program was designed to produce data on which to base a precision and bias statement for quantitative analysis by EDS. Nine laboratories were sent specimens of two well characterized materials, a type 308 stainless steel, and a complex mechanical alloy from Inco Alloys International, Inconel® MA 6000. The stainless steel was chosen as an example of a straightforward analysis with no special problems. The mechanical alloy was selected because elements were present in a wide range of concentrations; K, L, and M lines were involved; and Ta was severely overlapped with W. The test aimed to establish limits of precision that could be routinely achieved by capable laboratories operating under real world conditions. The participants were first allowed to use their own best procedures, but later were instructed to repeat the analysis using specified conditions: 20 kV accelerating voltage, 200s live time, ∼25% dead time and ∼40° takeoff angle. They were also asked to run a standardless analysis.

scholarly journals Trace element limitation of lymph nodes structure according to the x-ray fluorescent analysis with synchrotron radiation (SR XRF)

2020 ◽  
Author(s):  
O. V. Gorchakova ◽  
Yu. P. Kolmogorov ◽  
V. N. Gorchakov ◽  
G. A. Demchenko ◽  
S. N. Abdreshov
Keyword(s):  
Synchrotron Radiation ◽  
Lymph Nodes ◽  
Trace Element ◽  
X Ray ◽  
Fluorescent Analysis ◽  
Sr Xrf

Cryogenic high-resolution X-ray spectrometers for SR-XRF and microanalysis

1998 ◽  
Vol 5 (3) ◽  
pp. 515-517 ◽  
Author(s):  
M. Frank ◽  
C. A. Mears ◽  
S. E. Labov ◽  
L. J. Hiller ◽  
J. B. le Grand ◽  
...  
Keyword(s):  
High Resolution ◽  
Energy Resolution ◽  
Superconducting Tunnel Junction ◽  
Semiconductor Detectors ◽  
X Rays ◽  
X Ray ◽  
Sr Xrf ◽  
Demonstration Experiment ◽  
Near Future ◽  
Stj Detector

Experimental results are presented obtained with a cryogenically cooled high-resolution X-ray spectrometer based on a 141 × 141 µm Nb-Al-Al2O3-Al-Nb superconducting tunnel junction (STJ) detector in an SR-XRF demonstration experiment. STJ detectors can operate at count rates approaching those of semiconductor detectors while still providing a significantly better energy resolution for soft X-rays. By measuring fluorescence X-rays from samples containing transition metals and low-Z elements, an FWHM energy resolution of 6–15 eV for X-rays in the energy range 180–1100 eV has been obtained. The results show that, in the near future, STJ detectors may prove very useful in XRF and microanalysis applications.

SR XRF Analysis for studying plants in an area of geological heterogeneity

2012 ◽  
Vol 6 (3) ◽  
pp. 454-457 ◽  
Author(s):  
E. P. Khramova ◽  
I. G. Boyarskikh ◽  
O. V. Chankina ◽  
K. P. Kutsenogii
Keyword(s):  
Geological Heterogeneity ◽  
Xrf Analysis ◽  
Sr Xrf

scholarly journals Peran Kontaminasi Kerak pada Diferensiasi Magma Pembentuk Batuan Vulkanik Sungai Ampalas, Mamuju, Sulawesi Barat

EKSPLORIUM ◽  
2020 ◽  
Vol 41 (2) ◽  
pp. 73
Author(s):  
Windi Anarta Draniswari ◽  
Sekar Indah Tri Kusuma ◽  
Tyto Baskara Adimedha ◽  
I Gde Sukadana
Keyword(s):  
Magma Mixing ◽  
Volcanic Rocks ◽  
Geochemical Characteristics ◽  
X Ray ◽  
Radioactive Mineral ◽  
Alkaline Feldspar ◽  
High Alkalinity ◽  
Preliminary Study ◽  
Xrf Analyses

ABSTRAK Anomali radiometri telah ditemukan di area Sungai Amplas pada bongkah batuan vulkanik. Nilai yang terukur dari spektrometer gama adalah 787 ppm eU dan 223 ppm eTh. Penemuan ini menarik untuk pengembangan eksplorasi. Studi lebih lanjut diperlukan untuk mengetahui karekteristik batuan pembawa mineral radioaktif dari sampel in-situ. Penelitian ini bertujuan untuk mengetahui karakteristik petrologi dan geokimia batuan vulkanik Ampalas sebagai studi awal untuk mengetahui proses akumulasi mineral radioaktif pada batuan vulkanik Ampalas. Metodologi yang digunakan meliputi pengamatan lapangan, pengambilan sampel batuan, analisis petrografi dan X-Ray Fluorescence (XRF). Batuan vulkanik ampalas tersusun atas ponolit, foidit, dan foid-syenit. Tekstur batuannya terdiri dari porfiritik, aliran, rim piroksen, zoning, pseudo-leusit, korosi, inklusi mafik, dan sieve. Karakteristik geokimia menunjukkan alkalinitas tinggi dan indikasi pengayaan mineral radioaktif yang tersebar dalam batuan. Proses magmatis yang berperan dalam pembentukan batuan vulkanik adalah fraksionasi kristal (fraksionasi leusit dan alkali felspar), asimilasi kerak kontinen, dan pencampuran magma. Interaksi antara magma dan kerak menyebabkan diferensiasi magma berkelanjutan yang menghasilkan akumulasi uranium dan torium lebih tinggi.ABSTRACT Anomalous radiometry has been found in Ampalas River Area on volcanic rock boulder. The values measured from gamma spectrometer are 787 ppm eU and 223 ppm eTh. This discovery is promising for exploration development. Further study need to figure the radioactive mineral bearing rock characteristic from in-situ samples. The research aim is to determine the petrology and geochemical characteristics of Ampalas volcanic rocks as preliminary study to find radioactive mineral accumulation process of Ampalas volcanic rocks. The methodologies are field observation, rock sampling, petrography, and X-Ray fluorescence (XRF) analyses. The Ampalas volcanic rocks consist of phonolite, phoidite, and phoid syenite. Their textures are porphyritic, flow, pyroxene rim, zoning, pseudo-leucite, corrosion, mafic inclusions, and sieve. The geochemical characteristics show high alkalinity and radioactive mineral enrichment disseminating on rock. The magmatic processes which play a significant role in radioactive mineral-bearing rocks formation are crystal fractionations (leucite and alkaline feldspar fractionations), continental crust assimilation, and magma mixing. Long interaction between magma and crust creates advanced magma differentiation causing higher uranium and thorium accumulation.  

scholarly journals Study on Western Asiatic cast ribbed rectangular beads from Kaman-Kalehöyük, Turkey, by using portable X-ray fluorescence

2013 ◽  
Vol 1 (1) ◽  
pp. 23
Author(s):  
Izumi Nakai ◽  
Kriengkamol Tantrakarn ◽  
Yoshinari Abe ◽  
Sachihiro Omura
Keyword(s):  
Bronze Age ◽  
Principal Component ◽  
Glass Beads ◽  
Late Bronze Age ◽  
Ancient Trade ◽  
Western Asia ◽  
Material Evidence ◽  
Excavation Site ◽  
Plant Ash ◽  
Xrf Analyses

In this article we report a comparative study on excavated objects and artifact from museums to reveal an aspect of ancient trade. The target artifact is Western Asiatic cast ribbed rectangular beads excavated from an architectural remain at Kaman-Kalehöyük, Turkey. Blue glass beads of this type have been excavated in Western Asia from north Iran and Iraq to the Syro-Palestinian coast from second half of 16th to 14th century BC. The analysis of the samples was carried out by using a portable Xray fluorescence (XRF) spectrometer developed by us. The instrument was brought to the excavation site in Turkey as well as to the museums to analyse typologically similar glass beads from the collection of Okayama Orient Museum and MIHO MUSEUM in Japan, for comparison. Our XRF analyses suggested that all analysed glass artifacts are plant ash sodalime silica glass with 2-4 wt% magnesium and potassium. The three glass beads exhibited similar compositional characteristic, i.e. they contain Sb, Pb, Fe, Cu and Sr in similar quantities. A typological and principal component analysis comparison of the glass beads unearthed from Kaman- Kalehöyük site with those of the museums and literature data support that they should have a similar origin. In addition, archaeological context of the glass from Kaman-Kalehöyük also supports that the artifact belongs to the Middle-Late Bronze Age (16th to 15th centuries BC). This is the first scientific material evidence that shows the possibility of a cultural flow from Mesopotamia region to Kaman-Kalehöyük during Middle- Late Bronze Age.

scholarly journals Forensic Discrimination of Aluminum Foil by SR-XRF and ICP-AES

2010 ◽  
Vol 59 (6) ◽  
pp. 537-541 ◽  
Author(s):  
Masaaki Kasamatsu ◽  
Yasuhiro Suzuki ◽  
Shinichi Suzuki ◽  
Naoki Miyamoto ◽  
Seiya Watanabe ◽  
...  
Keyword(s):  
Aluminum Foil ◽  
Sr Xrf
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