Electrostatic Interaction between Ionic Polymer Grafted Surfaces Studied by Atomic Force Microscopy

1997 ◽  
Vol 188 (2) ◽  
pp. 431-438 ◽  
Author(s):  
Junfeng Zhang ◽  
Emiko Uchida ◽  
Yoshikimi Uyama ◽  
Yoshito Ikada
Keyword(s):  
Atomic Force Microscopy ◽  
Electrostatic Interaction ◽  
Ionic Polymer ◽  
Force Microscopy ◽  
Atomic Force

Study of characteristics of electrostatic interaction between RNases and mica surface using atomic force microscopy

2011 ◽  
Vol 6 (7-8) ◽  
pp. 510-515 ◽  
Author(s):  
O. A. Konovalova ◽  
N. V. Kalacheva ◽  
F. V. Shirshikov ◽  
M. Kh. Salakhov
Keyword(s):  
Atomic Force Microscopy ◽  
Electrostatic Interaction ◽  
Mica Surface ◽  
Force Microscopy ◽  
Atomic Force

scholarly journals An NC-AFM and KPFM study of the adsorption of a triphenylene derivative on KBr(001)

2012 ◽  
Vol 3 ◽  
pp. 221-229 ◽  
Author(s):  
Antoine Hinaut ◽  
Adeline Pujol ◽  
Florian Chaumeton ◽  
David Martrou ◽  
André Gourdon ◽  
...  
Keyword(s):  
Atomic Force Microscopy ◽  
Electrostatic Interaction ◽  
Room Temperature ◽  
Surface Molecule ◽  
Kelvin Probe ◽  
Force Microscopy ◽  
Atomic Force ◽  
Strong Intermolecular Interaction ◽  
Cyano Groups ◽  
Molecule Interaction

The adsorption on KBr(001) of a specially designed molecule, consisting of a flat aromatic triphenylene core equipped with six flexible propyl chains ending with polar cyano groups, is investigated by using atomic force microscopy in the noncontact mode (NC-AFM) coupled to Kelvin probe force microscopy (KPFM) in ultrahigh vacuum at room temperature. Two types of monolayers are identified, one in which the molecules lie flat on the surface (MLh) and another in which they stand approximately upright (MLv). The Kelvin voltage on these two structures is negatively shifted relative to that of the clean KBr surface, revealing the presence of surface dipoles with a component pointing along the normal to the surface. These findings are interpreted with the help of numerical simulations. It is shown that the surface–molecule interaction is dominated by the electrostatic interaction of the cyano groups with the K+ ions of the substrate. The molecule is strongly adsorbed in the MLh structure with an adsorption energy of 1.8 eV. In the MLv layer, the molecules form π-stacked rows aligned along the polar directions of the KBr surface. In these rows, the molecules are less strongly bound to the substrate, but the structure is stabilized by the strong intermolecular interaction due to π-stacking.

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