Abstract
A large-eddy simulation model is adopted to investigate the evolution of scalars transported by atmospheric cloud-free convective boundary layer flows. Temperature fluctuations due to the ground release of sensible heat and concentration fluctuations of a trace gas emitted at the homogeneous surface are mixed by turbulence within the unstable boundary layer. On the top, the entrainment zone is varied to obtain two distinct situations: (i) the temperature inversion is strong and the trace gas increment across the entrainment region is small, yielding to a small top flux with respect to the surface emission; (ii) the temperature inversion at the top of the convective boundary layer is weak, and the scalar increment large enough to achieve a concentration flux toward the free atmosphere that overwhelms the surface flux. In both cases, an estimation of the entrainment flux is obtained within a simple model, and it is tested against numerical data. The evolution of the scalar profiles is discussed in terms of the different entrainment–surface flux ratios.
Results show that, when entrainment at the top of the boundary layer is weak, temperature and trace gas scalar fields are strongly correlated, particularly in the lower part of the boundary layer. This means that they exhibit similar behavior from the largest down to the smallest spatial scales. However, when entrainment is strong, as moving from the surface, differences in the transport of the two scalars arise.
Finally, it is shown that, independently of the scalar regime, the temperature field exhibits more intermittent fluctuations than the trace gas.
Similarity of Scalar Fields in the Convective Boundary Layer
