Copper Catalyzed Oxidative Carbonylation of Methanol to Dimethyl Carbonate

1988 ◽  
pp. 215-232 ◽  
Author(s):  
G. Lee Curnutt ◽  
A. Dale Harley
Keyword(s):  
Dimethyl Carbonate ◽  
Oxidative Carbonylation

scholarly journals Environmental Assessment of Dimethyl Carbonate Production: Comparison of a Novel Electrosynthesis Route Utilizing CO2 with a Commercial Oxidative Carbonylation Process

2016 ◽  
Vol 4 (4) ◽  
pp. 2088-2097 ◽  
Author(s):  
Isabel Garcia-Herrero ◽  
Rosa Marisa Cuéllar-Franca ◽  
Víctor Manuel Enríquez-Gutiérrez ◽  
Manuel Alvarez-Guerra ◽  
Angel Irabien ◽  
...  
Keyword(s):  
Environmental Assessment ◽  
Dimethyl Carbonate ◽  
Oxidative Carbonylation ◽  
Carbonate Production

Oxidative Carbonylation of Methanol to Dimethyl Carbonate by Chlorine-Free Homogeneous and Immobilized 2,2'-Bipyrimidine Modified Copper Catalyst

2007 ◽  
Vol 72 (8) ◽  
pp. 1094-1106 ◽  
Author(s):  
Szilárd Csihony ◽  
László T. Mika ◽  
Gábor Vlád ◽  
Katalin Barta ◽  
Christian P. Mehnert ◽  
...  
Keyword(s):  
High Pressure ◽  
Dimethyl Carbonate ◽  
Copper Catalyst ◽  
Catalytic Performance ◽  
Spectroscopic Studies ◽  
Oxidative Carbonylation ◽  
Cu Catalyst

A chlorine-free catalyst, prepared in situ from Cu(II) acetate and 2,2'-bipyrimidine, can be used for the oxidative carbonylation of methanol to dimethyl carbonate. In situ high pressure IR and NMR spectroscopic studies suggest the formation of [Cu(2,2'-bipyrimidine)(CO)- (OMe)] as one of the key intermediates. The catalytic performance of the 2,2'-bipyrimidine-modified Cu-catalyst is similar to the CuCl-based system. The chlorine free catalyst can be immobilized by using the copolymer of 5-vinyl-2,2'-bipyrimidine and styrene.

Oxidative Carbonylation of Methanol to Dimethyl Carbonate Over Cu(II)–1,10-Phenanthroline Bromide Complexes

2014 ◽  
Vol 22 (10) ◽  
pp. 1117-1121 ◽  
Author(s):  
Zhiping Du ◽  
Lihua Xiong ◽  
Zhikun Lin ◽  
Xuli Li ◽  
Yigang Ding ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
Oxidative Carbonylation

scholarly journals Evolution of the pore and framework structure of NaY zeolite during alkali treatment and its effect on methanol oxidative carbonylation over a CuY catalyst

2020 ◽  
Vol 44 (11-12) ◽  
pp. 710-720
Author(s):  
Lifei Yan ◽  
Tingjun Fu ◽  
Jiajun Wang ◽  
Nilesh Narkhede ◽  
Zhong Li
Keyword(s):  
Catalytic Activity ◽  
Surface Area ◽  
Photoelectron Spectroscopy ◽  
Dimethyl Carbonate ◽  
Alkali Treatment ◽  
Oxidative Carbonylation ◽  
Framework Structure ◽  
Y Zeolite ◽  
Cage Structure ◽  
X Ray

Alkali treatment is widely used on aluminosilicate zeolites with high Si/Al ratios in order to fabricate mesopores in the framework. However, for zeolites with low Si/Al ratios, the effect of alkali treatment on the pore and framework structure needed further study. In this work, Y zeolite is treated with NaOH solutions of different concentrations and is used as the support for Cu-based catalysts for oxidative carbonylation of methanol to dimethyl carbonate. The physicochemical properties of the supports and corresponding catalysts are characterized by N2 adsorption–desorption, X-ray diffraction, X-ray fluorescence, transmission electron microscopy, inductively coupled plasma mass spectrometry, X-ray photoelectron spectroscopy, and H2-temperature-programmed reduction analyses. The results show that no obvious mesopores are formed under alkali treatment, even at high NaOH concentration. However, amorphous species present in the micropores of Y zeolite are removed, which increases the micropore surface area as well as the crystallinity. Simultaneously, the cage structure is partially destroyed, which also leads to a slight increase of the pore volume and surface area. The altered micropore structure eventually increases the content and accessibility of the exchanged Cu species, which is beneficial to the catalytic activity. When the concentration of NaOH is 0.6 M, the space time yield of dimethyl carbonate for the corresponding catalyst was 151.4 mg g−1 h−1 which is 3.3-fold higher than that of the untreated-Y-zeolite-supported Cu catalyst. However, further increasing the alkali treatment strength can seriously destroy the basic aluminosilicate structure of the Y zeolite and decrease its intrinsic ion-exchange capacity. This results in the formation of agglomerated CuO on the catalyst surface, which was not conducive to catalytic activity.

Carbon nanotube-supported Cu-based catalysts for oxidative carbonylation of methanol to methyl carbonate: effect of nanotube pore size

2020 ◽  
Vol 10 (8) ◽  
pp. 2615-2626 ◽  
Author(s):  
Dan Zhao ◽  
Guoqiang Zhang ◽  
Lifei Yan ◽  
Lingqi Kong ◽  
Huayan Zheng ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbon Nanotube ◽  
Pore Size ◽  
Dimethyl Carbonate ◽  
Oxidative Carbonylation ◽  
Inner Diameter ◽  
Methyl Carbonate

The inner diameter of CNTs significantly affected the location, dispersion, autoreduction and stability of Cu species and thus the catalytic activity and stability for oxidative carbonylation of methanol to dimethyl carbonate.

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