Development of Environmental-Friendly Lead-Free Piezoelectric Materials for Actuator Uses

Author(s):  
Hiroaki Takeda ◽  
Enzhu Li ◽  
Takashi Nishida ◽  
Takuya Hoshina ◽  
Takaaki Tsurumi
2011 ◽  
Vol 01 (03) ◽  
pp. 269-288 ◽  
Author(s):  
YI-QING LU ◽  
YONG-XIANG LI

There are a large number of research publications on the hot topic of environmental friendly lead-free piezoelectric materials worldwide in the last decade. The number of researchers and institutions involved from China is much larger than other countries or regions. The publications by Chinese researchers cover a broad spectrum on the preparations, structures, properties and applications of lead-free piezoelectric ceramics. This has motivated us to come out with a review on recent advances in development of lead-free piezoelectric ceramics in China. The emphases are especially on the preparation and electric properties of barium titanate-based materials, bismuth sodium titanate and related materials, alkaline niobate and related materials, bismuth layer-structured materials, as well as texture engineering of ceramics and some of their single crystals. Hopefully, this could give further impetus to the researchers to continue their efforts in this promising area and also draw the attentions from legislature, research office, industrial and publics.


2006 ◽  
Vol 510-511 ◽  
pp. 842-845 ◽  
Author(s):  
Noriko Bamba ◽  
Kentaro Kato ◽  
Toshinori Taishi ◽  
Takayuki Hayashi ◽  
Keigo Hoshikawa ◽  
...  

Langasite (La3Ga5SiO14: denoted by LGS) single crystal is one of the lead free piezoelectric materials with high piezoelectricity that is maintained up to its melting point (1470°C). Although LGS single crystals have usually been grown by Czochralski (CZ) method in oxygen contained atmosphere to prevent evaporation of Ga, they were grown by the vertical Bridgman (VB) method in Ar atmosphere without oxygen, and their properties were evaluated in this work. Transparent and colorless LGS single crystals were successfully obtained without Ga evaporation by the VB method in Ar atmosphere, and their resistivity at room temperature was much higher than that grown by conventional CZ method. Piezoelectric constant d11 of the crystal grown by the VB method was 6 x 10-12 C/N, which was close to that of the crystal grown by CZ method. The colorless transparent LGS single crystal turned to orange and its resistivity decreased by annealing in air. Since an orange-colored transparent LGS single crystal has been grown by conventional CZ method, this indicates that color change and the resistivity decrease of LGS crystal is caused by extra interstitial oxygen atoms in the crystal.


Author(s):  
Xiaolin Huang ◽  
Peng Tan ◽  
Yu Wang ◽  
Yao Zhang ◽  
Xiangda Meng ◽  
...  

Improvement of durability is greatly important for the practical applications of lead-free-doped piezoelectric materials. However, the promotional mechanism of anti-fatigue properties and the impact on local structures from ion dopants...


2010 ◽  
Vol 03 (01) ◽  
pp. 79-81 ◽  
Author(s):  
BAOJIN CHU ◽  
WENYI ZHU ◽  
NAN LI ◽  
L. ERIC CROSS

Flexoelectricity describes the physical phenomenon of the generation of electric polarization from mechanical strain gradient in solid insulators. In common dielectric materials, the flexoelectric coefficient is trivially small ~10-10 C/m. In Ba(Sr,Ti)O 3 (BST) ceramics, flexoelectric coefficient up to 10-4 C/m was observed. Such high coefficient makes it possible to design high piezoelectric response flexoelectric composites. In this letter, we will demonstrate that the newly designed flexoelectric composites could have piezoelectric properties better than conventional piezoelectric materials.


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