Indirect Determination of Hydraulic Properties of Porous Media

1993 ◽  
pp. 37-50
Author(s):  
J. R. Cannon ◽  
Paul DuChateau
Keyword(s):  
Porous Media ◽  
Hydraulic Properties ◽  
Indirect Determination

Indirect Determination of Amikacin by Gold Nanoparticles as Redox Probe

2020 ◽  
Vol 17 ◽  
Author(s):  
Mansureh Alizadeh ◽  
Mandana Amiri ◽  
Abolfazl Bezaatpour
Keyword(s):  
Gold Nanoparticles ◽  
Bacterial Infections ◽  
Limit Of Detection ◽  
Pharmaceutical Preparation ◽  
Cathodic Peak ◽  
Easy Method ◽  
Peak Current ◽  
Indirect Determination ◽  
Tract Infections

: Amikacin is an aminoglycoside antibiotic used for many gram-negative bacterial infections like infections in the urinary tract, infections in brain, lungs and abdomen. Electrochemical determination of amikacin is a challenge in electroanalysis because it shows no voltammetric peak at the surface of bare electrodes. In this approach, a very simple and easy method for indirect voltammetric determination of amikacin presented in real samples. Gold nanoparticles were electrodeposited at the surface of glassy carbon electrode in constant potential. The effect of several parameters such as time and potential of deposition, pH and scan rates on signal were studied. The cathodic peak current of Au3+ decreased with increasing amikacin concentration. Quantitative analysis of amikacin was performed using differential pulse voltammetry by following cathodic peak current of gold ions. Two dynamic linear ranges of 1.0 × 10−8–1.0 × 10-7 M and 5.0 × 10−7–1.0 × 10-3 M were obtained and limit of detection was estimated 3.0× 10−9 M. The method was successfully determined amikacin in pharmaceutical preparation and human serum. The effect of several interference in determination of amikacin was also studied.

Determination of Some Nitrophenols by Atomic Absorption Spectrometry (AAS) After Extraction of Ionic Associates Involving the Bipyridylocopper(II) or Phenanthrolinocopper(II) Complex

1994 ◽  
Vol 59 (10) ◽  
pp. 2227-2234 ◽  
Author(s):  
Václav Stužka ◽  
Jaromír Souček
Keyword(s):  
Molecular Weight ◽  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Methyl Isobutyl Ketone ◽  
Absorption Spectrometry ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Indirect Determination ◽  
Ionic Associates

A new method has been developed for the indirect determination of nitroso- and nitrophenols by atomic absorption spectrometry (AAS) after extraction of ionic associates involving bipyridylocopper(II) (CuDP) or phenanthrolinocopper(II) (CuPH) complexes. Nitrobenzene and methyl isobutyl ketone appeared to be suitable for the extraction. It was possible to determine several tenths to hundredths of a milligram of nitrophenol in a litre. Extractable associates with CuDP and CuPH are formed by phenols possessing two substituents or by higher molecular weight phenols such as naphthol or hydroxyquinoline. Monosubstituted phenols fail to form associates of this kind.

Acid Interferences in Indirect Determination of Silicon bt Atomic Absorption Spectroscopy (AAS)

1974 ◽  
Vol 7 (12) ◽  
pp. 627-635
Author(s):  
A. Radecki ◽  
H. Lamparczyk ◽  
J. Grzybowski ◽  
J. Halkiewicz
Keyword(s):  
Atomic Absorption ◽  
Absorption Spectroscopy ◽  
Atomic Absorption Spectroscopy ◽  
Indirect Determination

scholarly journals Experimental investigation to characterize simple versus multi scaling analysis of hydraulic conductivity at a mesoscale

2021 ◽  
Author(s):  
Guglielmo Federico Antonio Brunetti ◽  
Samuele De Bartolo ◽  
Carmine Fallico ◽  
Ferdinando Frega ◽  
Maria Fernanda Rivera Velásquez ◽  
...  
Keyword(s):  
Hydraulic Conductivity ◽  
Spatial Variability ◽  
Hydraulic Properties ◽  
Scaling Laws ◽  
Scaling Analysis ◽  
Field Scale ◽  
Porous Formation ◽  
Proper Design ◽  
First Time

AbstractThe spatial variability of the aquifers' hydraulic properties can be satisfactorily described by means of scaling laws. The latter enable one to relate the small (typically laboratory) scale to the larger (typically formation/regional) ones, therefore leading de facto to an upscaling procedure. In the present study, we are concerned with the spatial variability of the hydraulic conductivity K into a strongly heterogeneous porous formation. A strategy, allowing one to identify correctly the single/multiple scaling of K, is applied for the first time to a large caisson, where the medium was packed. In particular, we show how to identify the various scaling ranges with special emphasis on the determination of the related cut-off limits. Finally, we illustrate how the heterogeneity enhances with the increasing scale of observation, by identifying the proper law accounting for the transition from the laboratory to the field scale. Results of the present study are of paramount utility for the proper design of pumping tests in formations where the degree of spatial variability of the hydraulic conductivity does not allow regarding them as “weakly heterogeneous”, as well as for the study of dispersion mechanisms.

Indirect determination of aluminum (III) in water samples by in-electrode coulometric titration

2021 ◽  
Vol 164 ◽  
pp. 106058
Author(s):  
Jakub Masac ◽  
Jan Lovic ◽  
Ernest Beinrohr ◽  
Frantisek Cacho
Keyword(s):  
Water Samples ◽  
Coulometric Titration ◽  
Indirect Determination
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