The symmetry properties of the Dirac equation, which describes electrons in relativistic quantum mechanics, is rather different from that of the corresponding Schr6dinger equation. Consequently, even when the velocity of light, c, is much larger than the velocity of an electron Vk, with wave vector, k, relativistic effects may be important. For instance, while the exchange interaction is isotropic in non-relativistic quantum mechanics the coupling between spin and orbital degrees of freedom in relativistic quantum mechanics implies that the band structure of a spin polarized metal depends on the orientation of its magnetization with respect to the crystal axis. As a consequence there is a finite set of degenerate directions for which the total energy of the electrons is an absolute minimum. Evidently, the above effect is the principle mechanism of the magneto crystalline anisotropy [1]. The following session will focus on this and other qualitatively new relativistic effects, such as dichroism at x-ray frequencies [2] or Fano effects in photo-emission from non-polarized solids [3].
A family of analytically solvable Schrödinger equations related by Levi-Civita transformation
