Source-Receptor Relationships for Trace Elements in Northern Europe

1986 ◽  
pp. 825-835 ◽  
Author(s):  
Jozef M. Pacyna
2005 ◽  
Vol 44 (9) ◽  
pp. 1421-1435 ◽  
Author(s):  
J. Timothy Dvonch ◽  
Gerald J. Keeler ◽  
Frank J. Marsik

Abstract Source–receptor relationships for mercury (Hg) and other trace elements wet deposited in southeastern Florida were investigated using daily event precipitation samples collected over a 1-yr period in 1995–96. Data collected in Davie, Florida, showed significantly higher (2.2 times) volume-weighted mean (VWM) Hg concentrations during the spring and summer seasons relative to winter. A meteorological tracer analysis, utilizing the ratio of trace elements lanthanum (La) to cerium (Ce), determined that “feed” air to precipitation cells arriving at the site incorporated local urban emissions more frequently during the spring and summer seasons. Using Weather Surveillance Radar-1988 Doppler (WSR-88D) data, analysis of precipitation-cell path histories for events collected at 17 sites in southeastern Florida over 1 month in the summer of 1995 showed significantly higher (2.0 times) VWM Hg concentrations in events with easterly cell paths than in those with westerly paths for storms arriving at Everglades sites. Significantly higher VWM concentrations for known anthropogenic elements vanadium (V) and nickel (Ni) (oil combustion) and lead (Pb) and antimony (Sb) (waste incineration) were also observed in events with easterly paths. In addition, events arriving from the east (offshore) that impacted the coastal sites were significantly lower in Hg (a factor of 2.6) than were events from the east that impacted the urban sites (after events moved inland over emission sources). This study demonstrates that source–receptor relationships can be established by analyzing the meteorological conditions corresponding to each precipitation event, and it supports the previous finding that local anthropogenic sources played the dominant role in the wet deposition of Hg to southern Florida and the Everglades during the study period.


Author(s):  
O.T. Woo ◽  
G.J.C. Carpenter

To study the influence of trace elements on the corrosion and hydrogen ingress in Zr-2.5 Nb pressure tube material, buttons of this alloy containing up to 0.83 at% Fe were made by arc-melting. The buttons were then annealed at 973 K for three days, furnace cooled, followed by ≈80% cold-rolling. The microstructure of cold-worked Zr-2.5 at% Nb-0.83 at% Fe (Fig. 1) contained both β-Zr and intermetallic precipitates in the α-Zr grains. The particles were 0.1 to 0.7 μm in size, with shapes ranging from spherical to ellipsoidal and often contained faults. β-Zr appeared either roughly spherical or as irregular elongated patches, often extending to several micrometres.The composition of the intermetallic particles seen in Fig. 1 was determined using Van Cappellen’s extrapolation technique for energy dispersive X-ray analysis of thin metal foils. The method was employed to avoid corrections for absorption and fluorescence via the Cliff-Lorimer equation: CA/CB = kAB · IA/IB, where CA and CB are the concentrations by weight of the elements A and B, and IA and IB are the X-ray intensities; kAB is a proportionality factor.


Author(s):  
D. A. Carpenter ◽  
Ning Gao ◽  
G. J. Havrilla

A monolithic, polycapillary, x-ray optic was adapted to a laboratory-based x-ray microprobe to evaluate the potential of the optic for x-ray micro fluorescence analysis. The polycapillary was capable of collecting x-rays over a 6 degree angle from a point source and focusing them to a spot approximately 40 µm diameter. The high intensities expected from this capillary should be useful for determining and mapping minor to trace elements in materials. Fig. 1 shows a sketch of the capillary with important dimensions.The microprobe had previously been used with straight and with tapered monocapillaries. Alignment of the monocapillaries with the focal spot was accomplished by electromagnetically scanning the focal spot over the beveled anode. With the polycapillary it was also necessary to manually adjust the distance between the focal spot and the polycapillary.The focal distance and focal spot diameter of the polycapillary were determined from a series of edge scans.


1993 ◽  
Vol 57 (4) ◽  
pp. 312-317
Author(s):  
NH Wilson ◽  
A Richards ◽  
J Laverock ◽  
MS Purkiss

1979 ◽  
Vol 7 (6) ◽  
pp. 1330-1331
Author(s):  
E. D. WILLS

2010 ◽  
pp. 100080510134803
Author(s):  
Valerie Brown
Keyword(s):  

2004 ◽  
Vol 74 (4) ◽  
pp. 247-251 ◽  
Author(s):  
Lombardi-Boccia ◽  
Lanzi ◽  
Lucarini ◽  
Di Lullo

This study was undertaken to estimate the contribution of meat and meat products consumption to the daily intakes of trace elements (Fe, Zn, Cu, Se), heme iron, and selected B vitamins (thiamine, riboflavin, niacin) in Italy. Meat and meat products were selected on the basis of their consumption frequency reported by the most recent nationwide dietary individual survey carried out in Italy (INN-CA study). The daily intakes of total iron and heme iron were 1.65 and 1.13 mg/person/day. Zinc intake was 3.65 mg/person/day. Beef made the main contribution to iron, heme iron, and zinc daily intakes. Copper daily intake was 107.3 mug/person/day, with meat products provided the highest contribution (40 mug/person/day). Daily intake of selenium (7.14 mug/person/day) was provided mainly by poultry consumption. Thiamine intake was 228 mug/person/day, and meat products were the main source (110 mug/person/day). Riboflavin intake was 136 mug/person/day, with both beef and meat products as the main contributors (40 mug/person/day). Niacin intake was 7.53 mg/person/day, and poultry was the main source (2.28 mg/person/day). Meat and meat products were a valuable source of micronutrients, supplying 47, 48, and 24% of zinc, niacin, and thiamin daily requirements, respectively, and over 10% of iron, copper, selenium, and riboflavin daily average requirement values of the italian RDAs calculated for the population involved in the survey (INN-CA study).


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