Infrared Studies on Anesthetic Compounds

Author(s):  
C. Sandorfy ◽  
G. Trudeau
Keyword(s):  
1980 ◽  
Vol 4 (1) ◽  
pp. 90-92
Author(s):  
P. J. McGregor ◽  
A. R. Hyland

The 30 Doradus region offers an excellent opportunity to study cluster formation processes and recent star formation in the Large Magellanic Cloud.


Langmuir ◽  
1989 ◽  
Vol 5 (2) ◽  
pp. 330-332 ◽  
Author(s):  
V. A. Howarth ◽  
M. C. Petty ◽  
G. H. Davies ◽  
J. Yarwood

1969 ◽  
Vol 47 (6) ◽  
pp. 901-910 ◽  
Author(s):  
Paul Buckley ◽  
Paul A. Giguère ◽  
Michel Schneider

The relative intensities of the C—X stretching bands of the gauche and trans isomers in the vapor were measured as a function of temperature up to 165 °C for 2-chloroethanol, and up to 130 °C for 2-bromoethanol. From these the enthalpy differences between the two isomers were found to be 1.20 and 1.45 ± 0.1 kcal mole−1 respectively for the two halogenated ethanols. Similar measurements on the O—H stretching bands gave values higher than the above by 0.45 kcal mole−1 for both compounds. This apparent discrepancy is interpreted as due to a second gauche isomer, the OH group of which is not engaged in intramolecular hydrogen bonding, and which is less stable than the trans isomer.A study of the isotopic molecule ClCH2—CH2OD has led to unambiguous assignment of the OH bending and torsional frequencies. The spectra of the solid show that 2-chloroethanol can exist in two different crystalline phases: a stable one consisting of gauche molecules only, and a metastable one containing both isomers.


2001 ◽  
Vol 56 (5) ◽  
pp. 381-385
Author(s):  
Z. Akdeniz ◽  
M . Gaune-Escard ◽  
M. P. Tosi

Abstract We determine a model of the ionic interactions in RF3 compounds, where R is a rare-earth element in the series from La to Lu, by an analysis of data on the bond length and the vibrational mode frequencies of the PrF3, GdF3 and HoF3 molecular monomers. All RF3 monomers are predicted to have a pyramidal shape, displaying a progressive flattening of the molecular shape in parallel with the lanthanide contraction of the bond length. The vibrational frequencies of all monomers are calculated, the results being in good agreement with the data from infrared studies of matrix-isolated molecules. We also evaluate the geometrical structure and the vibrational spectrum of the La2F6 and Ce2F6 dimers, as a further test of the proposed model. -PACS 36.40.Wa (Charged clusters)


2010 ◽  
Vol 83 (10-11) ◽  
pp. 931-941 ◽  
Author(s):  
V. Goian ◽  
S. Kamba ◽  
C. Kadlec ◽  
D. Nuzhnyy ◽  
P. Kužel ◽  
...  
Keyword(s):  

1971 ◽  
Vol 9 (1-2) ◽  
pp. 77-90 ◽  
Author(s):  
C.J.H. Schutte ◽  
D.J.J. Van Rensburg

Sign in / Sign up

Export Citation Format

Share Document