Dynamic and Variational Approaches to the River Regime Relation

Author(s):  
A. Lamberti
1988 ◽  
Vol 53 (9) ◽  
pp. 1919-1942 ◽  
Author(s):  
Josef Paldus ◽  
Paul E. S. Wormer ◽  
Marc Benard

The performance of various variational and non-variational approaches to the many-electron correlation problem is examined for a simple four-electron model system consisting of two stretched hydrogen molecules in trapezoidal, rectangular and linear configurations, in which the degree of quasi-degeneracy can be continuously varied from a non-degenerate to an almost degenerate situation. In contrast to an earlier work (K. Jankowski and J. Paldus, Int. J. Quantum Chem. 18, 1243 (1980)) we employ a double-zeta plus polarization basis and examine both single reference and multireference configuration interaction and coupled-cluster-type approaches. The performance of various Davidson-type corrections is also investigated.


2016 ◽  
Vol 61 (7) ◽  
pp. 931-968 ◽  
Author(s):  
Shapour Heidarkhani ◽  
Ghasem A. Afrouzi ◽  
Massimiliano Ferrara ◽  
Shahin Moradi

Author(s):  
Shapour Heidarkhani ◽  
Ghasem A. Afrouzi ◽  
Shahin Moradi

In this paper, we consider the existence of one solution and three solutions for the boundary value system with Sturm–Liouville boundary conditions [Formula: see text] for [Formula: see text]. Our technical approach is based on variational methods. In addition, examples are provided to illustrate our results.


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