Concocting Nanostructured Plant Molecules for Inhibiting the Corrosion Activity in HYSD Bars

Author(s):  
G. K. Monica Nandini ◽  
N. Gokul ◽  
Bipin Chandra ◽  
Khalid
Keyword(s):  
2019 ◽  
Vol 24 (4) ◽  
pp. 59-66
Author(s):  
E.S. Filatov

Corrosion behavior of metal alloys in a melt of potassium chloroaluminate (KAlCl4) was investigated. Metal aluminum was used as a protector for protection against continuous frontal corrosion. The equilibrium potentials of aluminum and the corrosion potential of the alloys were measured. The data were obtained to evaluate the corrosion ability of the system of molten salt of potassium chloroaluminate - gas (argon) by measuring the redox potential of the specified environment depending on the composition of the gas atmosphere above it, i.e. from impurities of water vapor, hydrochloric acid, oxygen and other, for example, carbonaceous gases. The calculations of the protection efficiency using the potential difference between the metal aluminum and the protected material were performed. The regularities of changes in the equilibrium potentials of aluminum from the temperature and concentration were established as the fundamental data for possible use at determining the composition ratio of potassium chlorides and aluminum in potassium chloroaluminate as input data for the development of a sensor of composition of chloroaluminate potassium.


2021 ◽  
Vol 32 ◽  
pp. 100662 ◽  
Author(s):  
Abdelhadi Louroubi ◽  
Ali Hasnaoui ◽  
Youssef Ait Aicha ◽  
Nayad Abdallah ◽  
Rachid Idouhli ◽  
...  
Keyword(s):  

Author(s):  
Menno T. van Os ◽  
Piet van Mastrigt ◽  
Andrew Francis

A significant part of the high pressure gas transport system of Gasunie cannot be examined by in-line inspection techniques. To ensure safe operation of these pipelines, an External Corrosion Direct Assessment (ECDA) module for PIMSLIDER (a pipeline integrity management system) is currently under development. The functional specifications of this module are based on NACE RP0502-2002, a recommended practice for ECDA. In addition to this, a new probabilistic methodology has been adopted, to take account for uncertainties associated with ECDA and to quantify the contributions from aboveground surveys and excavations to the integrity of a pipeline. This methodology, which is based on Structural Reliability Analysis (SRA) and Bayesian updating techniques, is presented in more detail in paper IPC2006-10092 of this conference. The DA module of PIMSLIDER enables computerized storage, retrieval and processing of all appropriate pipeline data and therefore guarantees highly accurate, reproducible and time saving integrity analyses of the Gasunie grid. Another important function of this system is the ability to use the complete database of all pipelines to pre-assess the integrity of a particular pipeline. This automated retrieval of data from pipelines with similar characteristics and/or environmental conditions results in a substantial increase of accessible data and enables Gasunie to improve the reliability of applied statistics throughout the process. As a consequence, the overall cost of inspections and excavations can be greatly reduced. In the Pre-Assessment phase, the DA module assists the integrity manager in gathering and analyzing data necessary to determine the current condition of a pipeline. After collection and visualization of the available data, the user can identify suitable ECDA regions. Furthermore, the gathered data are used to construct prior distributions of parameters relevant to the SRA model, such as the number and size of corrosion defects and pipeline-related parameters. In the Indirect Inspections step, the DA module allows the user to store and analyze the data from aboveground surveys, in order to identify and define the severity of coating faults and areas at which corrosion activity may occur. The probabilistic methodology accounts for the individual performance of each applied survey technique in terms of missed defects and false indications, in general a major source of uncertainty in ECDA. In the Direct Examinations phase, excavations are carried out to collect data to assess possible corrosion activity. Subsequently, the ECDA module uses this information to update, among other things, the parameters concerning the performance of survey techniques, the number of defects and the corrosion rate. As a result, updated failure frequencies are calculated for each ECDA-region (after each excavation if required), which are then used by the DA module to advise the integrity manager if additional mitigating activities are necessary, or by defining a reassessment interval.


2013 ◽  
Vol 54 (3) ◽  
pp. 155-159 ◽  
Author(s):  
D. N. Togobitskaya ◽  
A. F. Khamkhot’ko ◽  
N. A. Tsivataya ◽  
D. A. Stepanenko

Author(s):  
H. Celik Ozyildirim ◽  
Stephen R. Sharp

Historically, the Virginia Department of Transportation (VDOT) has repaired chloride-contaminated reinforced concrete bridge substructure elements that contain vertical and overhead sections with either shotcrete or a conventional A3 (3,000 psi) or A4 (4,000 psi) concrete. This study investigated using self-consolidating concrete (SCC), which has a high flow rate, bonds well, has low permeability, and provides smooth surfaces, as another option. The study also explored the use of galvanic anodes to control corrosion activity in SCC repairs. In VDOT’s Lynchburg and Staunton Districts, SCC repairs were made with and without the use of galvanic anodes. This provided a means for determining the benefit of using the anodes. The needed repair areas were determined by visual observation and sounding. After 7 years of service, SCC repair areas with and without anodes did not exhibit corrosion activity; small vertical cracks were evident in the SCC but did not affect performance. The anodes can provide protection to the steel immediately adjacent to the repair areas. However, unrepaired concrete areas away from the patched area with anodes now require additional repairs. SCC can be successfully placed; however, attention should be paid to form pressure and slump loss. Selection of repair areas should be based on corrosion-related measurements such as half-cell or chloride content, rather than sounding. Progression of corrosion demonstrates the necessity of removing all chloride-contaminated concrete not just adjacent to, but also away from the reinforcement, as anodes in the repair area will provide protection only in a narrow area around the patch.


2019 ◽  
Vol 289 ◽  
pp. 03009
Author(s):  
Ulrich Schneck

Electrochemical chloride extraction (ECE) is meant to re-establish the corrosion protection of concrete for the embedded reinforcement by removing chloride non-destructively and by enhancing the alkalinity of the rebar surrounding concrete. Both effects depend on various parameters, such as concrete cover, rebar spacing, chloride profile (especially if chloride ingress is deeper than the outside rebar layer) and concrete permeability. Often these parameters require long or multi-stage treatments, which basically can achieve any desired target level of chloride profile and impressed charge, but become a costly solution after a while. The acceptance criteria mentioned in CEN TS 14038-2 clause 8.6 refer to the achieved chloride content and to the amount of impressed charge, which are the conventional, easy measurable, but not direct parameters for evaluating the corrosion activity. A third parameter – the re-measurement of potentials for assessing (intended) low potential gradients and more positive average potentials – requires some weeks to months of depolarization and evaporation of water, before such a measurement can be applied successfully. A promising approach for an instant performance testing after an ECE treatment has been made on several occasions with follow-up measurements of electrolyte resistance, polarization resistance and corrosion current. Convincing changes towards significantly lower corrosion activity could be obtained (and compared to known classified values) – regardless of sometimes high residual chloride and very wet concrete. These data could be verified when re-assessed after some weeks, so enhanced corrosion measurements seem to be a useful tool for either establishing that the designed treatment time has been sufficient or to check on possible earlier termination of the treatment during a running ECE.


2019 ◽  
Vol 54 (4) ◽  
pp. 496-500
Author(s):  
Z. V. Slobodyan ◽  
Z. М. Il’nyts’kyi ◽  
L. А. Mahlatyuk ◽  
R. B. Kupovych ◽  
І. V. Semenyuk
Keyword(s):  

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