Kinetics of chemically modified lignin peroxidase and enzymatic oxidation of aromatic nitrogen-containing compounds

1995 ◽  
Vol 42 (5) ◽  
pp. 675-681 ◽  
Author(s):  
R. Vazquez-Duhalt ◽  
D. W. S. Westlake ◽  
P. M. Fedorak
1996 ◽  
Vol 60 (11) ◽  
pp. 1805-1809 ◽  
Author(s):  
Shinichi Yoshida ◽  
Takashi Watanabe ◽  
Yoichi Honda ◽  
Masaaki Kuwahara

1988 ◽  
Vol 20 (11-12) ◽  
pp. 167-173 ◽  
Author(s):  
S. E. Strand ◽  
R. M. Seamons ◽  
M. D. Bjelland ◽  
H. D. Stensel

The kinetics of methane-oxidizing bioreactors for the degradation of toxic organics are modeled. Calculations of the fluxes of methane and toxic chlorinated hydrocarbons were made using a biofilm model. The model simulated the effects of competition by toxics and mediane on their enzymatic oxidation by the methane monooxygenase. Dual-competitive-substrate/diffusion kinetics were used to model biofilm co-metabolism, integrating equations of the following form:where S1 and S2 are the local concentrations of methane and toxic compound, respectively, and r and K are the maximum uptake rates and Monod coefficients, and x is the distance into the biofilm.


2018 ◽  
Vol 26 (2) ◽  
pp. 121-127 ◽  
Author(s):  
Baoping Zhang ◽  
Yun Liu ◽  
Zhongchen Ma ◽  
Meichen Guo ◽  
Bowen Shen

2008 ◽  
Vol 6 (4) ◽  
pp. 581-591 ◽  
Author(s):  
Lyudmila Belyakova ◽  
Oleksandra Shvets ◽  
Diana Lyashenko

AbstractThe present work investigates the adsorptive interactions of Hg(II) ions in aqueous medium with hydroxylated silica, aminopropylsilica and silica chemically modified by β-cyclodextrin. Batch adsorption studies were carried out with various agitation times and mercury(II) concentrations. The maximum adsorption was observed within 15–30 min of agitation. The kinetics of the interactions, tested with the model of Lagergren for pseudo-first and pseudo-second order equations, showed better agreement with first order kinetics (k1 = 3.4 ± 0.2 to 5.9 ± 0.3 min−1). The adsorption data gave good fits with Langmuir isotherms. The results have shown that β-cyclodextrin-containing adsorbent has the largest adsorption specificity to Hg(II): K L = 4125 ± 205 mmol−1. “β-cyclodextrin-NO3-” inclusion complexes with ratio 1: 1 and super molecules with composition C42H70O35 ⊎ 3 Hg(NO3)2 are formed on the surface of β-cyclodextrin-containing silica.


1993 ◽  
Vol 15 (7) ◽  
pp. 567-574 ◽  
Author(s):  
Z.C. Hu ◽  
R.A. Korus ◽  
C.R. Venkataramu ◽  
R.L. Crawford

1975 ◽  
Vol 147 (1) ◽  
pp. 175-177 ◽  
Author(s):  
T Brittain ◽  
C Greenwood

An investigation of the spectral and some kinetic properties of a chemically modified cytochrome c is presented. The kinetics of reduction by chromous ion and ascorbate are shown to be unchanged from that of the native molecule, as are the kinetics of NO binding. The effects of pH on the visible spectrum are discussed in terms of a possible change in the pattern of co-ordination of the molecule with changing pH.


2015 ◽  
Vol 19 (5) ◽  
pp. 1419-1425 ◽  
Author(s):  
Yunchai Wang ◽  
Yuan Li ◽  
Wenzhuo Shen ◽  
Yaru Pei ◽  
Jingjing Liu ◽  
...  

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