Angular-resolved energy distribution of secondary ions emitted from a silicon target sputtered by a xenon ion beam

1992 ◽  
Vol 55 (4) ◽  
pp. 359-363 ◽  
Author(s):  
C. Pellet ◽  
C. Desgranges ◽  
C. Schwebel ◽  
J. Aubert
1997 ◽  
Author(s):  
Christelle Philippe ◽  
Claude Laure ◽  
Andre Bouchoule ◽  
Christelle Philippe ◽  
Claude Laure ◽  
...  

The construction of a two-stage ion beam mass spectrometer is described. Ions formed by electron impact are focused into a beam which enters a reaction vessel containing neutral molecules at a relatively high pressure. Secondary ions formed by reaction between the primary ion beam and neutral molecules are repelled out at right angles to the primary beam into a conventional magnetic analyser. The instrument was calibrated using the known Ar + + Ar → Ar + Ar + electron transfer reaction. It was then used to study the reaction of acetylium (CH 3 CO + ) and nitronium (NO + 2 ) ions with aromatic compounds. The principal secondary ions were those involving electron transfer from the aromatic nucleus, but in addition ions of the type C 6 H 6 NO + 2 formed by addition of the primary ion to the aromatic compound were detected. However, the relative ‘yield’ of adduct ion from different aromatic compounds showed little correlation with the reactivity of these compounds towards acylation or nitration in solution.


2015 ◽  
Vol 1085 ◽  
pp. 139-142 ◽  
Author(s):  
Oleg V. Sergeev ◽  
Victor P. Sergeev ◽  
Marina V. Fedorischeva ◽  
Andrey V. Voronov

The X-ray and mass spectroscopy of secondary ions, the phase composition, the distribution of elements in the depth of coating on the basis Ti-Al-N treated by the (Cr+B) ion beam was studied. It was established that the ion implantation of B and Cr in TiAlN coating leads to changes in the chemical composition of the surface layer and the redistribution of the elements in the surface layer. This fact leads to change of tribological properties and microhardness.


1989 ◽  
Vol 53 (369) ◽  
pp. 3-24 ◽  
Author(s):  
S. J. B. Reed

AbstractIn ion microprobe analysis the specimen is bombarded with a focussed ion beam a few µm in diameter and the secondary ions produced are accelerated into the entrance slit of a mass spectrometer. An outline of the salient features of the instrument is given here, together with an account of the methods used for quantitative elemental and isotopic analysis.The major part of this paper consists of a comprehensive account of the geological applications of ion microprobe analysis. These include elemental analysis, especially for trace elements (down to sub-ppm levels in many cases) and light elements (H-F) which are beyond the scope of the electron microprobe. The other main area of geological interest is isotopic analysis, where the ion microprobe has the advantage over conventional mass spectrometry of being capable of in situ analysis of selected points on polished sections, obviating the need for laborious specimen preparation, and enabling spatially-resolved data to be obtained, with a resolution of a few µm. The ion microprobe has been especially successful in U-Pb zircon dating and the study of isotope anomalies in meteorites. Other significant applications include diffusion and stable isotope studies.


2010 ◽  
Vol 28 (3) ◽  
pp. 429-436 ◽  
Author(s):  
J.P. Xin ◽  
X.P. Zhu ◽  
M.K. Lei

AbstractEnergy deposition by high-intensity pulsed ion beam into a metal target has been studied with time-of-flight (TOF) of ions which can be related to the original ion kinetic energy E0 and the ion mass with $t_{\rm TOF} \propto 1/\sqrt{2E_{0}/m_{i}}$. It is found that the TOF effect has a profound influence on the kinetic energy distribution of implanted ions and subsequent energy deposition process into the target. The HIPIB of mixed H+ and C+ was extracted from a magnetically insulated ion diode at a peak accelerating voltage of 350 kV, leading to an ion current density of 300 A/cm2 at the target. The widespread ion energy spectrum remarkably varied in shape as arriving at the target surface, from the original Gaussian-like of 80-ns duration to a pulse form of a sharp front and a long tail extending to about 140-ns duration. Energy loss of the mixed ions into a Ti target was simulated utilizing a Monte Carlo method. The energy deposition generally showed a shallowing trend and could be divided into two phases proceeded with sequent arrivals of H+ and C+. Note that, the peak value of deposited energy profile appeared at the beginning of mixed ion irradiation phase, other than the phase of firstly arrived H+ with peak kinetic energy and peak ion current. This study indicated that TOF effect of ions greatly affects the HIPIB-matter interaction with a kinetic energy spectrum of impinging ions at the target, noticeably differing from that of original output of the ion source; consequently, the specific energy deposition phenomena of the widespread ion energy can be studied with the TOF correlation of ion energy and ion current, otherwise not obtainable in common cases assuming fixed ion energy distribution in accordance with the original source output.


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