Special features in spinning viscose fibre and yarns into a precipitation bath containing sulfuric acid and sodium sulfate

1987 ◽  
Vol 18 (6) ◽  
pp. 425-428
Author(s):  
V. P. Kim ◽  
M. M. Aref'eva ◽  
N. I. Solov'eva

1988 ◽  
Vol 19 (3) ◽  
pp. 247-248
Author(s):  
A. P. Rashevskii ◽  
T. A. Goncharova


Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 343 ◽  
Author(s):  
Dong Wang ◽  
Wenqiao Meng ◽  
Yunna Lei ◽  
Chunxu Li ◽  
Jiaji Cheng ◽  
...  

To improve sulfuric acid recovery from sodium sulfate wastewater, a lab-scale bipolar membrane electrodialysis (BMED) process was used for the treatment of simulated sodium sulfate wastewater. In order to increase the concentration of sulfuric acid (H2SO4) generated during the process, a certain concentration of ammonium sulfate solution was added into the feed compartment. To study the influencing factors of sulfuric acid yield, we prepared different concentrations of ammonium sulfate solution, different feed solution volumes, and different membrane configurations in this experiment. As it can be seen from the results, when adding 8% (NH4)2SO4 into 15% Na2SO4 under the experimental conditions where the current density was 50 mA/cm2, the concentration of H2SO4 increased from 0.89 to 1.215 mol/L, and the current efficiency and energy consumption could be up to 60.12% and 2.59 kWh/kg, respectively. Furthermore, with the increase of the volume of the feed compartment, the concentration of H2SO4 also increased. At the same time, the configuration also affects the final concentration of the sulfuric acid; in the BP-A-C-BP (“BP” means bipolar membrane, “A” means anion exchange membrane, and “C” means cation exchange membrane; “BP-A-C-BP” means that two bipolar membranes, an anion exchange membrane, and a cation exchange membrane are alternately arranged to form a repeating unit of the membrane stack) configuration, a higher H2SO4 concentration was generated and less energy was consumed. The results show that the addition of the double conjugate salt is an effective method to increase the concentration of acid produced in the BMED process.





2015 ◽  
Vol 78 (11) ◽  
pp. 1967-1972 ◽  
Author(s):  
BRITTNEY R. SCOTT ◽  
XIANG YANG ◽  
IFIGENIA GEORNARAS ◽  
ROBERT J. DELMORE ◽  
DALE R. WOERNER ◽  
...  

Studies were conducted to evaluate the efficacy of a commercial blend of sulfuric acid and sodium sulfate (SSS) in reducing Salmonella on inoculated whole chilled chicken wings and to compare its efficacy to peroxyacetic acid (PAA) and cetylpyridinium chloride (CPC). Wings were spot inoculated (5 to 6 log CFU/ml of sample rinsate) with a five-strain mixture of novobiocin- and nalidixic acid–resistant Salmonella and then left untreated (control) or treated by immersing individual wings in 350 ml of antimicrobial solution. An initial study evaluated two treatment immersion times, 10 and 20 s, of SSS (pH 1.1) and compared cell recoveries following rinsing of treated samples with buffered peptone water or Dey/Engley neutralizing broth. In a second study, inoculated wings were treated with SSS (pH 1.1; 20 s), PAA (700 ppm, 20 s), or CPC (4,000 ppm, 10 s) and analyzed for survivors immediately after treatment (0 h) and after 24 h of aerobic storage at 4°C. Color and pH analyses were also conducted in the latter study. Recovery of Salmonella survivors following treatment with SSS (10 or 20 s) was not (P ≥ 0.05) affected by the type of cell recovery rinse solution (buffered peptone water or Dey/Engley neutralizing broth), but there was an effect (P < 0.05) of SSS treatment time. Immersion of samples for 10 or 20 s in SSS resulted in pathogen reductions of 0.8 to 0.9 and 1.1 to 1.2 log CFU/ml, respectively. Results of the second study showed that there was an interaction (P < 0.05) between antimicrobial type and storage time. Efficacy against Salmonella at 0 h increased in the order CPC < SSS < PAA; however, after 24 h of aerobic storage, pathogen counts of SSS- and PAA-treated wings did not differ (P ≥ 0.05). Overall, the results indicated that SSS applied at pH 1.1 for 20 s was an effective antimicrobial intervention to reduce Salmonella contamination on chicken wings.



2016 ◽  
Vol 827 ◽  
pp. 275-278
Author(s):  
Martin Vyšvařil ◽  
Markéta Rovnaníková

The degradation of concrete due to ingress of sulfate ions from the environment plays an important role in the durability of concrete constructions, especially in sewage collection systems where concrete sewer pipes are exposed to sulfates from waste water and from biogenic activity of bacteria. During this process the pH of the surface of concrete sewer pipes is reduced and it may lead to the steel depassivation and results in the corrosion of steel reinforcement. Damage due to sulfate interaction can result in the cracking and softening, with loss of strength of concrete. This paper is focused on the sulfate attack on fine-grained concrete where the effect of one-year contact of 0.5% H2SO4, and 5% Na2SO4 on changes of pH and content of sulfates in 7 types of concrete has been analyzed. It was found that after one year of sulfate attack on concrete, significant growth of content of sulfates is observed in the lowermost layer of the samples. Samples treated by 5% Na2SO4 contain slightly more sulfates in the upper layers than samples treated by sulfuric acid. The reduction in pH of aqueous leaches occurred in all layers of the samples. However, even in the lower layers of the samples, the reduction of pH below 9.5 did not turn up (except for SRS sample), and thus the conditions for the depassivation of reinforcement were not met.



1972 ◽  
Vol 27 (10) ◽  
pp. 1258-1263
Author(s):  
Rainer Hamm ◽  
Manfred Lüdicke

The different radioautographic patterns were observed on the upper surface of fore wings of Inachis io L. when 35S-sodium sulfate, 3H-tryptophane and 14C-hydrolysed protein were orally applied or injected to the larvae or pupae of the butterfly.35S-sodium sulfate and 3H-tryptophane were found in ommochrome containing scale areas, whereas 14C-hydrolysed protein could be detected only in melanine containing scale areas by radioautographic methods. These results prove that the 35S-sodium sulfate can be utilized in the synthesis of ommatin D as ester of sulfuric acid.By means of particular UV-radiation the colour and form of wings were changed. This change is either due to the interruption of the flow of determination responsible for the formation of pattern or the blockage of lymphatic fluid. The radioautographic pattern of the treated wing shows also the change of form, colour and position of the scale areas.



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