Thermodynamic studies of dilute aqueous solutions of cyclic ethers and simple carbohydrates

1972 ◽  
Vol 1 (1) ◽  
pp. 3-16 ◽  
Author(s):  
F. Franks ◽  
J. R. Ravenhill ◽  
D. S. Reid
Keyword(s):  
Aqueous Solutions ◽  
Cyclic Ethers ◽  
Thermodynamic Studies ◽  
Dilute Aqueous Solutions ◽  
Simple Carbohydrates

Heat capacities and volumes of dilute aqueous solutions of 1,3-dioxane and trioxane

1981 ◽  
Vol 59 (17) ◽  
pp. 2599-2600 ◽  
Author(s):  
Gérald Perron ◽  
Jacques E. Desnoyers
Keyword(s):  
Aqueous Solutions ◽  
Concentration Dependence ◽  
Infinite Dilution ◽  
Unit Volume ◽  
Heat Capacities ◽  
Cyclic Ethers ◽  
Group Additivity ◽  
Simple Correlation ◽  
Dilute Aqueous Solutions ◽  
Molal Volumes

The densities and heat capacities per unit volume of 1,3-dioxane and trioxane were measured in water at 25 °C in the concentration range 0.1 to 1 mol kg−1. Apparent molal volumes [Formula: see text] and [Formula: see text] heat capacities were derived. The infinite dilution [Formula: see text] shows excellent group additivity with other cyclic ethers in water but the additivity is less satisfactory for[Formula: see text]. No simple correlation can be made for the concentration dependence of these functions.

The reactions of oligoalcohols with arsenic, arsenous, boric and germanic acids

1980 ◽  
Vol 45 (10) ◽  
pp. 2645-2655 ◽  
Author(s):  
Antonín Mikan ◽  
Miloš Bartušek
Keyword(s):  
Aqueous Solutions ◽  
Equilibrium Constants ◽  
Dilute Aqueous Solutions

The reactions of sorbitol, mannitol, adonitol, dulcitol, glucose and glycerol with H3AsO4, H3AsO3, H3BO3 and GeO2 acids in dilute aqueous solutions were studied by potentiometric neutralization titrations. The formation of the following chelates was demonstrated: As(V)L3-, As(III)L(OH)2-, HAs(III)L(OH)2, BL2-, GeL2(OH)- and GeL32- and the equilibrium constants for their formation were found. Conditions for formation of these chelates of organic oligohydroxy compounds are discussed.

Study of potential oscillations during reaction of an aluminium single crystal with an aqueous KOH solution

1990 ◽  
Vol 55 (2) ◽  
pp. 345-353 ◽  
Author(s):  
Ivan Halaša ◽  
Milica Miadoková
Keyword(s):  
Aqueous Solutions ◽  
Single Crystal ◽  
Single Crystals ◽  
Periodic Potential ◽  
Optimum Conditions ◽  
Potential Oscillations ◽  
Dilute Aqueous Solutions ◽  
Experimental Findings ◽  
Kinetics Of

The authors investigated periodic potential changes measured on oriented sections of Al single crystals during spontaneous dissolution in dilute aqueous solutions of KOH, with the aim to find optimum conditions for the formation of potential oscillations. It was found that this phenomenon is related with the kinetics of the reaction investigated, whose rate also changed periodically. The mechanism of the oscillations is discussed in view of the experimental findings.

scholarly journals Selective removal of lead ions from aqueous solutions using SiO2–MoO3: Isotherm, kinetics and thermodynamic studies

2021 ◽  
Vol 3 ◽  
pp. 100083
Author(s):  
Jasmina Sulejmanović ◽  
Neira Kovač ◽  
Mustafa Memić ◽  
Elma Šabanović ◽  
Sabina Begić ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Selective Removal ◽  
Lead Ions ◽  
Thermodynamic Studies ◽  
Kinetics And Thermodynamic

A tensammetric study of polyacrylamides, including their determination

1988 ◽  
Vol 66 (10) ◽  
pp. 2658-2663 ◽  
Author(s):  
Truis Smith-Palmer ◽  
Byron R. Wentzell ◽  
John C. Donini ◽  
Robert J. Jerrard
Keyword(s):  
Aqueous Solutions ◽  
Limits Of Detection ◽  
Dilute Aqueous Solutions ◽  
Phase Sensitive

Phase-sensitive tensammetry is shown to be a convenient and useful way to analyse polyacrylamides and associated derivatives (pams) in dilute aqueous solutions. Standard curves were obtained with ranges varying from 9 to 25 ppm and limits of detection varying from 0.7 to 2 ppm. Ways to change the range and sensitivity are discussed and demonstrated. Typical interferences and their effects are tabulated, and the analysis of pams in coal washings is discussed. The analysis of certain mixtures of polyacrylamides is shown to be possible.

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