Volume properties op ?-amino acids in limiting dilute aqueous solutions at different temperatures

Author(s):  
V. K. Abrosimov ◽  
G. V. Sibrina
2001 ◽  
Vol 56 (12) ◽  
pp. 832-836 ◽  
Author(s):  
S. B. Gadzuric ◽  
I. J. Zsigrai ◽  
R. M. Nikolic

Abstract The complex formation between lead(II) ions and chloride and bromide ions in melts of C a(N 03) 2 • 4 H2O • αCH3CONH2 has been studied at different temperatures between 30 and 70 °C. The formation constants of the complexes PbX+ and PbX2 (X = Cl, Br) were determined from em f measurements by means of Ag/AgX electrodes. The dependence of the formation constants for PbCl+ on the solvent melt composition has been analysed. The thermodynamic parameters ΔH011 and ΔS011 for PbX+ complex formation have been estimated. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated and anhydrous salt melts.


1956 ◽  
Vol 11 (4-5) ◽  
pp. 565-574 ◽  
Author(s):  
Judith Nosworthy ◽  
C.B. Allsopp

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