On the Correlation between liquid state structure and the self-diffusion coefficient in liquid metals

1975 ◽  
Vol 6 (6) ◽  
pp. 1294-1296 ◽  
Author(s):  
John P. Foster ◽  
Carole Daniels ◽  
Robert J. Reynik
Keyword(s):  
Diffusion Coefficient ◽  
Liquid State ◽  
Liquid Metals ◽  
The Self ◽  
State Structure ◽  
Self Diffusion ◽  
Self Diffusion Coefficient

Vacancy Formation Energy and Kinetic Properties of Liquid Metals

2021 ◽  
Vol 880 ◽  
pp. 43-48
Author(s):  
Yuri N. Starodubtsev ◽  
V.S. Tsepelev
Keyword(s):  
Diffusion Coefficient ◽  
Kinematic Viscosity ◽  
Formation Energy ◽  
Liquid Metals ◽  
Linear Regression Analysis ◽  
Vacancy Formation Energy ◽  
Vacancy Formation ◽  
Kinetic Properties ◽  
Self Diffusion ◽  
Self Diffusion Coefficient

We investigated the relationship of the vacancy formation energy with kinematic viscosity and self-diffusion coefficient in liquid metals at the melting temperature. Formulas are obtained that relate experimental values of the vacancy formation energy, kinematic viscosity, and self-diffusion coefficient to the atomic size and mass, the melting and Debye temperatures. The viscosity and self-diffusion parameters are introduced. The ratio of these parameters to vacancy formation energy is equal to dimensionless constants. It is shown that the formulas for viscosity and self-diffusion differ only in dimensionless constants; the values of these constants are calculated. Linear regression analysis was carried out and formulas with the highest adjusted coefficient of determination were identified. The calculated values of the self-diffusion coefficient for a large number of liquid metals are presented.

Investigation on the Diffusion Behavior of Mo-Ni Interface

2010 ◽  
Vol 152-153 ◽  
pp. 1607-1610 ◽  
Author(s):  
Wei Chan Cao ◽  
Shu Hua Liang ◽  
Yue Xin Xue ◽  
Xian Hui Wang
Keyword(s):  
Solid Solution ◽  
Diffusion Coefficient ◽  
Electron Microscope ◽  
Intermetallic Compound ◽  
Diffusion Layer ◽  
Interdiffusion Coefficient ◽  
The Self ◽  
Diffusion Behavior ◽  
Self Diffusion ◽  
Self Diffusion Coefficient

In order to gain a deep insight into the mechanism of Ni-doped Mo activated sintering process, the diffusion behavior of Mo-Ni interface was studied utilizing a Mo-Ni diffusion couple. The phase structure and composition on the diffusion layer were characterized and analyzed by means of scanning electron microscope and transmission electron microscope, the self diffusion coefficient and interdiffusion coefficient were calculated. The results show that a diffusion layer is formed between Mo and Ni after sintering at 1223k for 1h, which is comprised of a δ-NiMo intermetallic compound and a limit solid solution containing small amounts of nickel. The self diffusion coefficient and interdiffusion coefficient are 2.068×10-18cm2/s and 4.5×10-12cm2/s, respectively. It is suggested that the diffusion rate of Mo in δ-NiMo intermetallic compound and a limit solid solution containing small amounts of nickel is 106 times bigger than that of self diffusion, and the intermetallic compound layer provides a short diffusion path for Mo activated sintering.

Self-Diffusion in Molten Lithium Nitrate

1992 ◽  
Vol 47 (10) ◽  
pp. 1047-1050 ◽  
Author(s):  
C. Herdlicka ◽  
J. Richter ◽  
M. D. Zeidler
Keyword(s):  
Diffusion Coefficient ◽  
Diffusion Coefficients ◽  
Spin Echo ◽  
The Self ◽  
Lithium Nitrate ◽  
Equimolar Ratio ◽  
Self Diffusion ◽  
Field Gradients ◽  
Molten Lithium ◽  
Self Diffusion Coefficient

AbstractSelf-diffusion coefficients of 7Li+ ions have been measured in molten LiNO3 with several compositions of 6Li+ and 7Li+ over a temperature range from 537 to 615 K. The NMR spin-echo method with pulsed field gradients was applied. It was found that the self-diffusion coefficient depends on the isotopic composition and shows a maximum at equimolar ratio. At temperatures above 600 K this behaviour disappears.

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