Investigation of the separation of scandium and rare earth elements from red mud by use of reversed-phase HPLC

2004 ◽  
Vol 379 (5-6) ◽  
Author(s):  
LambriniV. Tsakanika ◽  
MariaTh. Ochsenk�hn-Petropoulou ◽  
LeonidasN. Mendrinos
2021 ◽  
Vol 171 ◽  
pp. 105645
Author(s):  
Sandeep Panda ◽  
Rachel Biancalana Costa ◽  
Syed Sikandar Shah ◽  
Srabani Mishra ◽  
Denise Bevilaqua ◽  
...  

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 500 ◽  
Author(s):  
Leonid Chaikin ◽  
Andrei Shoppert ◽  
Dmitry Valeev ◽  
Irina Loginova ◽  
Julia Napol’skikh

One of the potential sources of rare-earth elements (REE) is the industrial waste known as red mud (bauxite residue), in which the majority of REE from the initial bauxite are concentrated via the Bayer process. Therefore, the studies of the subject, both in Russia and outside, focus almost exclusively on red mud processing. This article looks into the possibility of REE concentration into red mud by leaching an intermediate product of the bauxite sintering process at Russian alumina refineries, namely electrostatic precipitator (ESP) dust. The experimental works were performed by X-ray diffraction (XRD)and electron probe microanalysis (EPMA) of the sinter and sinter dust. The determination of major and rare-earth elements in the sinter from the rotary kilns and in the ESP dust before and after leaching was carried out by X-ray fluorescence (XRF) and plasma mass spectrometry (ICP-MS). The study showed that it is possible to obtain red mud that contains three times more REE than traditional waste red mud after two-stage leaching ESP dust in the water at 95 °C followed by leaching in an alkaline-aluminate liquor at 240 °C. The shrinking core model was used to study the kinetics of leaching of the original ESP dust and water-treated dust in alkaline-aluminate liquor. The study showed the change in the limiting stage of the alkaline leaching process after water treatment, with the activation energy growing from 24.98 to 33.19 kJ/mol.


2019 ◽  
Vol 60 (4) ◽  
pp. 335-340 ◽  
Author(s):  
Upendra Singh ◽  
S. A. Thawrani ◽  
M. S. Ansari ◽  
S. P. Puttewar ◽  
A. Agnihotri

The Analyst ◽  
1983 ◽  
Vol 108 (1290) ◽  
pp. 1102 ◽  
Author(s):  
C. G. Yeole ◽  
V. M. Shinde

1990 ◽  
Vol 29 (11-12) ◽  
pp. 579-582 ◽  
Author(s):  
M. Adachi ◽  
K. Oguma ◽  
R. Kuroda

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Franziska Klimpel ◽  
Michael Bau ◽  
Torsten Graupner

AbstractScandium is a critical raw material that is essential for the EU economy because of its potential application in enabling technologies such as fuel cells and lightweight materials. As there is currently no secure supply of Sc, several projects worldwide evaluate potential Sc sources. While elsewhere in Europe emphasis is placed upon secondary resources such as red mud, we investigated the potential of industrial garnet sand and its waste products. Since Sc readily substitutes for Mg and Fe in the crystal lattice of garnet, the garnet minerals almandine and pyrope, in particular, may show high Sc concentrations. Garnet sand, after being used as an abrasive in the cutting and sandblasting industry, is recycled several times before it is finally considered waste which eventually must be disposed of. Extraction of Sc (and rare earth elements, REE) from such garnet sand may generate added value and thereby reduce disposal cost. The studied garnet sands from different mines in Australia, India and the U.S., and industrial garnet sands commercially available in Germany from different suppliers show average Sc concentrations of 93.7 mg/kg and 90.7 mg/kg, respectively, i.e. similar to red mud. Our data also show that “fresh” and recycled garnet sands yield similar Sc concentrations. Within the framework of a minimum-waste approach, it may be feasible to utilize the industrial waste-product “garnet sand” as an unconventional source of Sc and REE, that reduces disposal cost.


Sign in / Sign up

Export Citation Format

Share Document