Biotechnological trends and market impact on the recovery of rare earth elements from bauxite residue (red mud) – A review

2021 ◽  
Vol 171 ◽  
pp. 105645
Author(s):  
Sandeep Panda ◽  
Rachel Biancalana Costa ◽  
Syed Sikandar Shah ◽  
Srabani Mishra ◽  
Denise Bevilaqua ◽  
...  
Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 500 ◽  
Author(s):  
Leonid Chaikin ◽  
Andrei Shoppert ◽  
Dmitry Valeev ◽  
Irina Loginova ◽  
Julia Napol’skikh

One of the potential sources of rare-earth elements (REE) is the industrial waste known as red mud (bauxite residue), in which the majority of REE from the initial bauxite are concentrated via the Bayer process. Therefore, the studies of the subject, both in Russia and outside, focus almost exclusively on red mud processing. This article looks into the possibility of REE concentration into red mud by leaching an intermediate product of the bauxite sintering process at Russian alumina refineries, namely electrostatic precipitator (ESP) dust. The experimental works were performed by X-ray diffraction (XRD)and electron probe microanalysis (EPMA) of the sinter and sinter dust. The determination of major and rare-earth elements in the sinter from the rotary kilns and in the ESP dust before and after leaching was carried out by X-ray fluorescence (XRF) and plasma mass spectrometry (ICP-MS). The study showed that it is possible to obtain red mud that contains three times more REE than traditional waste red mud after two-stage leaching ESP dust in the water at 95 °C followed by leaching in an alkaline-aluminate liquor at 240 °C. The shrinking core model was used to study the kinetics of leaching of the original ESP dust and water-treated dust in alkaline-aluminate liquor. The study showed the change in the limiting stage of the alkaline leaching process after water treatment, with the activation energy growing from 24.98 to 33.19 kJ/mol.


2016 ◽  
Vol 164 ◽  
pp. 125-135 ◽  
Author(s):  
Panagiotis Davris ◽  
Efthymios Balomenos ◽  
Dimitrios Panias ◽  
Ioannis Paspaliaris

2019 ◽  
Vol 60 (4) ◽  
pp. 335-340 ◽  
Author(s):  
Upendra Singh ◽  
S. A. Thawrani ◽  
M. S. Ansari ◽  
S. P. Puttewar ◽  
A. Agnihotri

2019 ◽  
Vol 5 (1) ◽  
pp. 57-68 ◽  
Author(s):  
Rodolfo Marin Rivera ◽  
Ghania Ounoughene ◽  
Annelies Malfliet ◽  
Johannes Vind ◽  
Dimitris Panias ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Franziska Klimpel ◽  
Michael Bau ◽  
Torsten Graupner

AbstractScandium is a critical raw material that is essential for the EU economy because of its potential application in enabling technologies such as fuel cells and lightweight materials. As there is currently no secure supply of Sc, several projects worldwide evaluate potential Sc sources. While elsewhere in Europe emphasis is placed upon secondary resources such as red mud, we investigated the potential of industrial garnet sand and its waste products. Since Sc readily substitutes for Mg and Fe in the crystal lattice of garnet, the garnet minerals almandine and pyrope, in particular, may show high Sc concentrations. Garnet sand, after being used as an abrasive in the cutting and sandblasting industry, is recycled several times before it is finally considered waste which eventually must be disposed of. Extraction of Sc (and rare earth elements, REE) from such garnet sand may generate added value and thereby reduce disposal cost. The studied garnet sands from different mines in Australia, India and the U.S., and industrial garnet sands commercially available in Germany from different suppliers show average Sc concentrations of 93.7 mg/kg and 90.7 mg/kg, respectively, i.e. similar to red mud. Our data also show that “fresh” and recycled garnet sands yield similar Sc concentrations. Within the framework of a minimum-waste approach, it may be feasible to utilize the industrial waste-product “garnet sand” as an unconventional source of Sc and REE, that reduces disposal cost.


Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 860
Author(s):  
Konstantina Pyrgaki ◽  
Vasiliki Gemeni ◽  
Christos Karkalis ◽  
Nikolaos Koukouzas ◽  
Petros Koutsovitis ◽  
...  

Μining waste, processing by-products and mine water discharges pose a serious threat to the environment as in many cases they contain high concentrations of toxic substances. However, they may also be valuable resources. The main target of the current review is the comparative study of the occurrence of rare earth elements (REE) in mining waste and mine water discharges produced from the exploitation of coal, bauxite, phosphate rock and other ore deposits. Coal combustion ashes, bauxite residue and phosphogypsum present high percentages of critical REEs (up to 41% of the total REE content) with ΣREY content ranging from 77 to 1957.7 ppm. The total REE concentrations in mine discharges from different coal and ore mining areas around the globe are also characterised by a high range of concentrations from 0.25 to 9.8 ppm and from 1.6 to 24.8 ppm, respectively. Acid mine discharges and their associated natural and treatment precipitates seem to be also promising sources of REE if their extraction is coupled with the simultaneous removal of toxic pollutants.


2016 ◽  
pp. 183-197 ◽  
Author(s):  
Panagiotis Davris ◽  
Efthymios Balomenos ◽  
Dimitrios Panias ◽  
Ioannis Paspaliaris

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