H-Point Standard Addition Method for Simultaneous Determination of Palladium and Cobalt

2004 ◽  
Vol 146 (3-4) ◽  
pp. 265-270 ◽  
Author(s):  
Habibollah Eskandari ◽  
Ghadamali Bagherian Dehaghi
Keyword(s):  
Simultaneous Determination ◽  
Standard Addition ◽  
Standard Addition Method ◽  
Addition Method

scholarly journals Simultaneous Determination of Eosin-Yellow and Ponceau-SUsingH-Point Standard Addition Method in Micellar Media

2012 ◽  
Vol 9 (1) ◽  
pp. 224-232
Author(s):  
Amandeep Kaur ◽  
Usha Gupta
Keyword(s):  
Simultaneous Determination ◽  
Standard Addition ◽  
Nickel Chloride ◽  
Standard Addition Method ◽  
Micellar Media ◽  
Addition Method ◽  
Real Samples ◽  
Ponceau S ◽  
Eosin Yellow

H-point standard addition method (HPSAM) is developed for simultaneous determination of eosin-Yand ponceau-s in micellar media. Nickel chloride (NiCl2) is used as chromogenic reagent for complexes formation of eosin-Yand ponceau-Sfood colorants. The measurements were carried out using sodium lauryl sulphate as a surfactant, in buffered solution at pH 6.0. The concentration range of 0.115-2.53 μg/mL of eosin-Yand 0.159-3.80 μg/mL of ponceau-S. The proposed procedures have been applied successfully for the simultaneous determination of eosin-Yand ponceau-Sin synthetic binary mixtures and real samples.

scholarly journals H-Point Standard Addition Method for Simultaneous Determination of Eosin and Erytrosine

2011 ◽  
Vol 8 (4) ◽  
pp. 1979-1985 ◽  
Author(s):  
Amandeep Kaur ◽  
Usha Gupta
Keyword(s):  
Binary Mixture ◽  
Simultaneous Determination ◽  
Standard Addition ◽  
Standard Addition Method ◽  
Micellar Media ◽  
Addition Method ◽  
Commercial Products ◽  
Food Dyes ◽  
Triton X

A new, simple, sensitive and selectiveH-point standard addition method (HPSAM) has been developed for resolving binary mixture of food colorants eosin and erythrosine, which show overlapped spectra. The method is based on the complexation of food dyes eosin and erythrosine with Fe(III) complexing reagent at pH 5.5 and solubilizing complexes in triton x-100 micellar media. Absorbances at the two pairs of wavelengths, 540 and 550 nm (when eosin acts as analyte) or 518 and 542 nm (when erythrosine act as analyte) were monitored. This method has satisfactorily been applied for the determination of eosin and erythrosine dyes in synthetic mixtures and commercial products.

scholarly journals Combination of First Derivative Spectrophotometry and H-Point Standard Addition Method for Simultaneous Determination of Guaifenesin and Theophylline in Cough Syrup

2011 ◽  
Vol 8 (3) ◽  
pp. 966-976 ◽  
Author(s):  
R. Hajian ◽  
N. Shams ◽  
Z. Davarpanah
Keyword(s):  
Simultaneous Determination ◽  
Binary Mixtures ◽  
Standard Addition ◽  
Standard Addition Method ◽  
Determination Method ◽  
Addition Method ◽  
First Derivative ◽  
First Derivative Spectrophotometry ◽  
Cough Syrup

Combination of first derivative spectrophotometric and H-point standard addition method (HPSAM) has been applied for simultaneous determination of guaifenesin and theophylline. First derivative signals at the two pairs of wavelengths, 282.0-290.2 nm and 277.4-287.8 nm were monitored with the addition of standard solutions of both guaifenesin and theophylline in the ratio of 1:1. The method is able to accurately determine guaifenesin and theophylline (1:5 to 10:1) mole ratios. Accuracy and reproducibility of the determination method on the various amounts of guaifenesin and theophylline with known concentrations were evaluated in their binary mixtures. The recommended procedure was successfully applied to some cough syrups and synthetic mixtures with satisfactory results.

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