scholarly journals Syn-metamorphic sulfidation of the Gamsberg zinc deposit, South Africa

Author(s):  
Stefan Höhn ◽  
Hartwig E. Frimmel ◽  
Westley Price

AbstractThe Mesoproterozoic Aggeneys-Gamsberg ore district, South Africa, is one of the world´s largest sulfidic base metal concentrations and well-known as a prime example of Broken Hill-type base metal deposits, traditionally interpreted as metamorphosed SEDEX deposits. Within this district, the Gamsberg deposit stands out for its huge size and strongly Zn-dominated ore ( >14 Mt contained Zn). New electron microprobe analyses and element abundance maps of sulfides and silicates point to fluid-driven sulfidation during retrograde metamorphism. Differences in the chemistry of sulfide inclusions within zoned garnet grains reflect different degrees of interaction of sulfides with high metal/sulfur-ratio with a sulfur-rich metamorphic fluid. Independent evidence of sulfidation during retrograde metamorphism comes from graphic-textured sulfide aggregates that previously have been interpreted as quenched sulfidic melts, replacement of pyrrhotite by pyrite along micro-fractures, and sulfides in phyllic alteration zones. Limited availability of fluid under retrograde conditions caused locally different degrees of segregation of Fe-rich sphalerite into Zn-rich sphalerite and pyrite, and thus considerable heterogeneity in sphalerite chemistry. The invoked sulfur-rich metamorphic fluids would have been able to sulfidize base metal-rich zones in the whole deposit and thus camouflage a potential pre-metamorphic oxidation. These findings support the recently established hypothesis of a pre-Klondikean weathering-induced oxidation event and challenge the traditional explanation of Broken Hill-type deposits as merely metamorphosed SEDEX deposits. Instead, we suggest that the massive sulfide deposits experienced a complex history, starting with initial SEDEX-type mineralization, followed by near-surface oxidation with spatial metal separation, and then sulfidation of this oxidized ore during medium- to high-grade metamorphism.

Author(s):  
T. Dzingai ◽  
B. McFadzean ◽  
M. Tadie ◽  
M. Becker

Ores from a single deposit may exhibit extensive variability in their mineralogy and texture. The ability to quantify this variability and link it to mineral processing performance is one of the primary goals of process mineralogy. This study focuses on the effect of alteration in three platinum group element ore samples from the Great Dyke in Zimbabwe - two of which were more pristine compared to the third, which was locally classified as 'oxidized' ore. These ores are known to be characterized by varying degrees of alteration, resulting in numerous challenges in flotation and affecting both grade and recovery. Alteration, by near-surface oxidation, of the valuable base metal sulphides and platinum group minerals resulted in lower flotation recoveries of Cu, Ni, Pt, and Pd. Evidence of incipient oxidation was more readily observed in the base metal sulphide assemblage than the platinum group mineral assemblage, even though the loss in recovery (because of oxidation) was most significant for Pd. Alteration through hydration resulted in a significant increase in mass pull and dilution of concentrate grade through the inadvertent recovery of naturally floating gangue comprising composite orthopyroxene and talc particles. In this study, the amount of naturally floating gangue was more strongly correlated with the talc grain size distribution than the grade of talc in the flotation feed. The oxidation and hydration alteration reactions are not necessarily mutually exclusive, although one may be more dominant than the other, giving rise to ore variability.


2021 ◽  
Author(s):  
Zhenyu Zhang ◽  
Patrick Laux ◽  
Joël Arnault ◽  
Jianhui Wei ◽  
Jussi Baade ◽  
...  

<p>Land degradation with its direct impact on vegetation, surface soil layers and land surface albedo, has great relevance with the climate system. Assessing the climatic and ecological effects induced by land degradation requires a precise understanding of the interaction between the land surface and atmosphere. In coupled land-atmosphere modeling, the low boundary conditions impact the thermal and hydraulic exchanges at the land surface, therefore regulates the overlying atmosphere by land-atmosphere feedback processes. However, those land-atmosphere interactions are not convincingly represented in coupled land-atmosphere modeling applications. It is partly due to an approximate representation of hydrological processes in land surface modeling. Another source of uncertainties relates to the generalization of soil physical properties in the modeling system. This study focuses on the role of the prescribed physical properties of soil in high-resolution land surface-atmosphere simulations over South Africa. The model used here is the hydrologically-enhanced Weather Research and Forecasting (WRF-Hydro) model. Four commonly used global soil datasets obtained from UN Food and Agriculture Organization (FAO) soil database, Harmonized World Soil Database (HWSD), Global Soil Dataset for Earth System Model (GSDE), and SoilGrids dataset, are incorporated within the WRF-Hydro experiments for investigating the impact of soil information on land-atmosphere interactions. The simulation results of near-surface temperature, skin temperature, and surface energy fluxes are presented and compared to observational-based reference dataset. It is found that simulated soil moisture is largely influenced by soil texture features, which affects its feedback to the atmosphere.</p>


2007 ◽  
Vol 42 (5) ◽  
pp. 537-549 ◽  
Author(s):  
Craig R. McClung ◽  
Jens Gutzmer ◽  
Nicolas J. Beukes ◽  
Klaus Mezger ◽  
Harald Strauss ◽  
...  
Keyword(s):  

Author(s):  
Б.Л. Пхарое ◽  
А.Н. Евдокимов

Северо-западный регион ЮАР до недавнего времени не являлся промышленно марганценосным. Однако результаты изучения последних лет дают основание думать, что здесь могут быть залежи марганцевых руд. Марганцевое оруденение в этом регионе встречается в виде марганцевых конкреций, порошкообразного марганцевого вада и марганцевых корок в коре выветривания. Марганцевые конкреции приурочены к аллювиальной части «Westwits alluvium» рудного разреза и марганцевый вад накоплялся в карстовых структурах, образовавшихся в результате приповерхностного выветривания, выщелачивания и растворения подстилающих марганценосных неоархейских доломитов. Предполагается два потенциальных источника марганца: первый расположен непосредственно под рудным телом, а второй – на существенном удалении от него. Если первый источник рудного вещества поставлял марганец из подстилающих доломитов в процессе их выветривания, то второй вариант подразумевает существенный перенос металла из неизвестных коренных источников, расположенных на значительном удалении от области рудонакопления. Таким образом, для решения этого вопроса, необходимо провести экспериментальные исследования, изучающие природу, минералогию и источник сноса терригенных отложений «вмещающих материалов» верхнего рудного разреза. Цель работы – уточнить природу марганценосных терригенных залежей «Westwits alluvium» и, что самое важное, определить их коренной источник поступления и собственно минеральный состав. Методики исследования включали: петрографическое описание пород, геохимические анализы методами XRF и SEM, подсчеты объемного состава детритовых минералов и анализ дискриминационных диаграмм. Результаты. В результате проведенных исследований было установлено, что терригенные зёрна в основном представлены кварцем. Содержание полевых шпатов, минералов цемента и глинистых минералов не более 20 %. Использована классификация составов терригенного материала, основанная на подсчете в объемных процентах зерен кварца, полевого шпата, обломочных зерен других пород (вулканических, магматических и метаморфических пород), слюды и др. По этим данным были определены вероятные источники сноса, которыми являются породы Рэнд-Антиклинального хребта, расположенного к югу от изучаемого региона, а также архейские граниты, гнейсы и мафические-ультрамафические породы Каапваальского кратона. Осадконакопление происходило в низменной равнине с тропическим умеренно влажным и субгумидным климатом. Здесь, при повышенном рН воды происходило интенсивное выщелачивание пород и замещение детритовых зерен разного минерального состава диоксидом марганца. Ключевые слова: марганцовистый аллювий, третичный, терригенные отложения, Каапваальский кратон, Южная Африка The North-West region of the Republic of South Africa was previously not considered to constitute of manganese mineralization of industrial value. However, recently published articles indicated the presence of secondary manganese mineralization in the weathering crust, underlain by the manganiferous Neoarchean dolomites. Manganese mineralization in this region occurs in the form of manganese nodules, powdered manganese wad, and manganese crusts. Manganese nodules are confined to the alluvial part of the ore section known as the «Westwits alluvium» and manganese wad is accumulated in karstic structures formed as a result of near-surface weathering, leaching, and dissolution of underlying manganese-bearing Neoarchean dolomites. Two potential sources of manganese are assumed: the first relates to the dolomites which are located directly under the ore body, and the second relates to the source areas of terrigenous deposits. If the first hypothesis suggests that manganese ore substances were supplied from the underlying dolomites during their weathering, the second option then implies a significant transfer of metal from unknown root sources located at a considerable distance from the area of ore accumulation. Thus, it is necessary to conduct petrographic study to reconstruct their source regions and understand the close relations with Mn mineralization. Aim is to clarify the nature of the manganese-bearing terrigenous deposits «Westwits alluvium» and, most importantly, to determine their root source of supply and the actual mineral composition. Methodology of study includes mainly: petrographic study of rocks, geochemical analyses with the use of XRF and SEM methods, modal compositional analysis of the detrital minerals, and analysis of discrimination diagrams. Results. As a result of the conducted research, it was found that terrigenous grains consist mainly of detrital quartz grains. The content of feldspars, cement minerals and clay minerals seldom exceeds 20 %. The classification of terrigenous material based on the calculation of the volumetric percentage of the detrital framework grains: quartz, feldspar, clastic grains of other rocks types (volcanic, igneous and metamorphic rocks), mica, indicated probable source areas of the terrigenous sediments. These include metasedimentary rocks of the Rand Anticline Ridge which is located south of the studied region, and Archean granites, gneisses, and mafic-ultramafic rocks of the Kaapvaal Craton. In the basin of deposition, sedimentation occurred in a lowland plain within tropical region, characterized by moderately humid and sub-humid climatic conditions. These conditions, combined with oxidation and increased pH of the basin waters, contributed to the replacement of detrital grains with manganese dioxide


1972 ◽  
Vol 38 (297) ◽  
pp. 570-578 ◽  
Author(s):  
Evan R. Phillips ◽  
D. M. Ransom ◽  
R. H. Vernon

SummaryRetrograde metamorphism of gneisses and pegmatites leads in part to the destruction of feldspar and its replacement by late-stage lobate myrmekite and muscovite. Reactions promoted by retrogression suggest a range in volume of quartz production that may supplement that developed by exsolution and lead to deviations from the strict proportionality relationship suggested by previous workers. There is no need, however, to propose that quartz in myrmekite originates by constriction of pre-existing quartz within exsolved albite.


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