scholarly journals Impact of poly(vinyl alcohol) adsorption on the surface characteristics of mixed oxide Mn x O y –SiO2

Adsorption ◽  
2015 ◽  
Vol 22 (4-6) ◽  
pp. 417-423 ◽  
Author(s):  
M. Wiśniewska ◽  
V. Bogatyrov ◽  
I. Ostolska ◽  
K. Szewczuk-Karpisz ◽  
K. Terpiłowski ◽  
...  
Author(s):  
M. Wiśniewska ◽  
S. Chibowski ◽  
T. Urban ◽  
G. Fijałkowska ◽  
M. Medykowska ◽  
...  

Abstract The adsorption and electrokinetic properties of hybrid silica materials composed of nickel and silicon oxides (NixOy-SiO2), characterized by different contents of nickel oxide (from 0.5 to 3 mmol/g SiO2), were examined. These solids were also modified by poly(vinyl alcohol) to change their surface characteristics. The polymer is non-toxic and very well soluble in water. Due to incomplete hydrolysis of the polymer acetate groups, its macromolecules become negatively charged. The limited range of studied pH (6–10) resulted from high solubility of nickel oxide at more acidic pH values. The spectrophotometric, surface charge and electrophoretic measurements indicated that PVA exhibits higher adsorption affinity for the surfaces of mixed oxide with a larger content of nickel in its structure. Moreover, the presence of polymeric layers on the solid surface influences considerably the structure of electrical double layer formed at the mixed oxide-aqueous solution interface.


Langmuir ◽  
2020 ◽  
Vol 36 (13) ◽  
pp. 3415-3424 ◽  
Author(s):  
Tsukasa Miyazaki ◽  
Noboru Miyata ◽  
Tessei Yoshida ◽  
Hiroshi Arima ◽  
Yoshihiro Tsumura ◽  
...  

2015 ◽  
Vol 356 ◽  
pp. 905-910 ◽  
Author(s):  
M. Wiśniewska ◽  
V. Bogatyrov ◽  
K. Szewczuk-Karpisz ◽  
I. Ostolska ◽  
K. Terpiłowski

2013 ◽  
Vol 11 (3) ◽  
pp. 446-456
Author(s):  
Tachita Vlad-Bubulac ◽  
Diana Serbezeanu ◽  
Ana-Maria Oprea ◽  
Ionela-Daniela Carja ◽  
Corneliu Hamciuc ◽  
...  

AbstractAbstract New polymer hydrogels based on partially phosphorylated poly(vinyl alcohol) (PVA/Phosphoester) have been prepared. Fourier transform infrared spectroscopy (FT-IR) was employed to confirm PVA/Phosphoester formation. Contact angle measurements were performed to evaluate the surface characteristics of the hydrogels. The PVA/Phosphoester hydrogels were co-networked with Chondroitin sulfate (CS) in various ratios by chemical crosslinking. The synthetic-natural mixed resulted semi-IPN hydrogels were structurally and morphologically investigated by ATR — FT-IR spectroscopy and scanning electron microscopy, respectively. The swelling behavior and dynamic moisture sorption capacity of the PVA/Phosphoester (p-methyl-phenyl phosphonic dichloride) (P3)-CS semi-IPN hydrogels were followed. It was found that the performance of the semi-IPN hydrogels was influenced by the CS. By kinetic studies, it has been shown that the swelling processes occurred by an anomalous transport mechanism. Graphical abstract


2013 ◽  
Vol 104 ◽  
pp. 358-366 ◽  
Author(s):  
Luiz H.S. Gasparotto ◽  
Eduardo G. Ciapina ◽  
Daniel A. Cantane ◽  
Janaina F. Gomes ◽  
Fabio H.B. Lima ◽  
...  

2016 ◽  
Vol 22 (2) ◽  
Author(s):  
Małgorzata WIŚNIEWSKA ◽  
Katarzyna SZEWCZUK-KARPISZ ◽  
Iwona OSTOLSKA ◽  
Konrad TERPIŁOWSKI ◽  
Dariusz STERNIK ◽  
...  

Langmuir ◽  
2003 ◽  
Vol 19 (23) ◽  
pp. 9968-9972 ◽  
Author(s):  
B. M. Budhlall ◽  
O. L. Shaffer ◽  
E. D. Sudol ◽  
V. L. Dimonie ◽  
M. S. El-Aasser

Sign in / Sign up

Export Citation Format

Share Document