scholarly journals Speeds of Sound in n-Hexane and n-Heptane at Temperatures from (233.33 to 353.21) K and Pressures up to 20 MPa

2020 ◽  
Vol 42 (2) ◽  
Author(s):  
Christian W. Scholz ◽  
Markus Richter

AbstractThe speed of sound in high-purity n-hexane and n-heptane was experimentally studied utilizing the double-path length pulse-echo technique. Measurements with each alkane were carried out at temperatures from (233 to 353) K with pressures up to 20 MPa. Considering the uncertainty contributions from temperature, pressure, path-length calibration, pulse timing and sample purity, the relative expanded combined uncertainty (k = 2) in the speed of sound in n-hexane ranges from (0.012 to 0.042) % over the investigated ranges of pressure and temperature; for n-heptane, the uncertainty varies from (0.014 to 0.018) %. The sound speed data measured in n-hexane were among the data used for the development of a new fundamental equation of state, which is, however, not described in this work. The experimental data of n-heptane can be considered appropriate for modeling purposes and validation of existing equations of state.

2021 ◽  
Vol 42 (5) ◽  
Author(s):  
Christian W. Scholz ◽  
Roland Span

AbstractWe report experimental speeds of sound in methanol. Measurements were conducted at temperatures from 233 to 353 K with pressures up to 20 MPa using the double-path length pulse-echo technique. The relative expanded combined uncertainty (k = 2) in measurement was estimated to vary from 0.012 to 0.014%, considering contributions from temperature, pressure, path length calibration, pulse timing, and purity of the sample. Experimental speeds of sound gained in the scope of this work were compared with the equation of state by de Reuck and Craven, as well as with further data from literature.


2021 ◽  
Vol 43 (1) ◽  
Author(s):  
Tobias Neumann ◽  
Elmar Baumhögger ◽  
Roland Span ◽  
Jadran Vrabec ◽  
Monika Thol

AbstractThe homogeneous density of the liquid phase is experimentally investigated for methyl diethanolamine. Data are obtained along five isotherms in a temperature range between 300 K and 360 K for pressures up to 95 MPa. Two different apparatuses are used to measure the speed of sound for the temperatures between 322 K and 450 K with a maximum pressure of 95 MPa. These measurements and literature data are used to develop a fundamental equation of state for methyl diethanolamine. The model is formulated in terms of the Helmholtz energy and allows for the calculation of all thermodynamic properties in gaseous, liquid, supercritical, and saturation states. The experimental data are represented within their uncertainties. The physical and extrapolation behavior is validated qualitatively to ensure reasonable calculations outside of the range of validity. Based on the experimental datasets, the equation of state is valid for temperatures from 250 K to 750 K and pressures up to 100 MPa.


2021 ◽  
Vol 50 (2) ◽  
pp. 023105
Author(s):  
Tim Eisenbach ◽  
Christian Scholz ◽  
Roland Span ◽  
Diego Cristancho ◽  
Eric W. Lemmon ◽  
...  

2021 ◽  
Vol 73 (09) ◽  
pp. 33-35
Author(s):  
Anup T. Hunnur

Fluid samples collected using either wireline or logging-while-drilling (LWD) formation-testing technology for reservoir fluid characterization have long been accepted as the most representative of reservoir fluid. This, though, comes with a caveat that the collected sample is clean and devoid of any mud-filtrate contamination. With both techniques performed soon after drilling a well, there is always a risk of contaminating the collected fluid with mud filtrate. Toward the goal of reducing this risk, since the early 2000s, technologies have been brought forth to help identify the fluid down hole. There have been multiple developments with sensors for absorbance spectroscopy, fluorescence, fluid resistivity, fluid refractive index, and so on. Each sensor development was targeted toward a specific fluid interaction with the mud filtrate, thereby helping to differentiate the reservoir fluid from the mud filtrate. Downhole sampling conditions can be classified into two broad groups: one case where the reservoir fluid is miscible with the mud filtrate and the other where the reservoir fluid is not miscible with the mud filtrate. The immiscible cases are generally straightforward, since sensors such as absorbance spectroscopy can easily differentiate among oil, water, and gas. In addition, the technique can be used to determine the fractional portion of each phase in the flow. Complications arise when the reservoir fluids happen to be miscible with the mud filtrate system; for example, while sampling reservoir water in the presence of water-based mud filtrate, absorbance spectroscopy by itself is unable to differentiate among the fluids. Table 1 provides generic information about different fluid systems as well as the sensors used to differentiate the fluids. While there are other sources of correlation-based fluid-property information, the basic sensors mentioned are the ones used for correlations. As mentioned, each sensor provides detailed information for specific cases, but only sound speed provides a single-sensor solution for the conditions expected. Sound-Speed (SS) Measurement While acoustic data have long been used for reservoir characterization, data have been used for fluid characterization during downhole sampling for only a decade. Experience has shown that this measurement is sensitive enough to not only differentiate injection water or formation water but also to track and quantify small changes in oil compressibility—an important step in focused sampling. The measurement uses a pulse-echo technique based on the principle that an acoustic signal propagates approximately as a plane wave, and that the speed of sound is based on the distance the pulse travels divided by the time it took to traverse the distance. (SPWLA-2013-FFF). The 10-MHz piezoelectric transducer is mounted onto a machined flat surface on the flowline of RCX (the wireline formation testing tool reservoir characterization instrument) as schematically shown in Fig. 1. The travel path length is the distance between the two internal surfaces of the flowline. The result was a bulk measurement of the speed of sound across all the fluid flowing though the flowline. The only calibration needed is for this path length, which can differ due to slight machining variations. A calibrated sensor was able to differentiate fluids which exhibited sound-speed differences as small as 4.7 m/sec (0.5 msec/ft of sound-speed slowness).


2022 ◽  
Vol 43 (3) ◽  
Author(s):  
Monika Thol ◽  
Florian Fenkl ◽  
Eric W. Lemmon

AbstractA fundamental equation of state in terms of the Helmholtz energy is presented for chloroethene (vinyl chloride). Due to its fundamental nature, it can be used to consistently calculate all thermodynamic state properties in the fluid region. Based on the underlying experimental database, it is valid from the triple-point temperature 119.31 K to 430 K with a maximum pressure of 100 MPa. In addition to the accurate reproduction of experimental data, correct extrapolation behavior during the development of the equation was attained. This enables the equation to be applied in modern mixture frameworks.


2018 ◽  
Vol 63 (7) ◽  
pp. 2533-2547 ◽  
Author(s):  
Monika Thol ◽  
Frithjof H. Dubberke ◽  
Elmar Baumhögger ◽  
Roland Span ◽  
Jadran Vrabec

2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Viorel Feroiu ◽  
Dan Geana ◽  
Catinca Secuianu

Vapour � liquid equilibrium, thermodynamic and volumetric properties were predicted for three pure hydrofluorocarbons: difluoromethane (R32), pentafluoroethane (R125) and 1,1,1,2 � tetrafluoroethane (R134a) as well as for binary and ternary mixtures of these refrigerants. Three cubic equations of state GEOS3C, SRK (Soave � Redlich � Kwong) and PR (Peng � Robinson) were used. A wide comparison with literature experimental data was made. For the refrigerant mixtures, classical van der Waals mixing rules without interaction parameters were used. The GEOS3C equation, with three parameters estimated by matching several points on the saturation curve (vapor pressure and corresponding liquid volumes), compares favorably to other equations in literature, being simple enough for applications.


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