scholarly journals Fluorescein-bridged Perylene Bisimide Dimer for Use as Liquid Crystal: Studies on Mesomorphic and Fluorescence Properties

Author(s):  
Mingguang Zhu ◽  
Meihui Chen ◽  
Hongyu Guo ◽  
Fafu Yang
2021 ◽  
Author(s):  
Mingguang Zhu ◽  
Meihui Chen ◽  
Hongyu Guo ◽  
Fafu Yang

Abstract A novel fluorescein-bridged perylene bisimide (PBI) dimer for liquid crystal (LC) with geometrically symmetric structure was developed. The mesomorphic results indicated that the energetically stable and unstable conformers of fluorescein fragments could lead to the transformation of mesophases from a hexagonal columnar mesophase to an uncertain phase at 136.9 °C in heating, whilst a stable hexagonal columnar mesophase maintained between 175.6 °C and 58.6 °C in cooling. The selectively excited fluorescence characters in THF solution demonstrated that the fluorescence resonance energy transfer (FRET) effect between fluorescein fragments and PBI unites could provide a means to effectively impose strong fluorescence of the dimeric PBIs modified with suitable chromophore at the N-imide position, which alternatively serves as a platform for the further study of multi-functional PBI-based LCs.


2017 ◽  
Vol 129 (8) ◽  
pp. 2194-2197 ◽  
Author(s):  
Stefanie Herbst ◽  
Bartolome Soberats ◽  
Pawaret Leowanawat ◽  
Matthias Lehmann ◽  
Frank Würthner

2003 ◽  
Vol 13 (4) ◽  
pp. 767-772 ◽  
Author(s):  
Ulrike Haas ◽  
Christoph Thalacker ◽  
Jörg Adams ◽  
Jürgen Fuhrmann ◽  
Silke Riethmüller ◽  
...  

2011 ◽  
Vol 21 (17) ◽  
pp. 3291-3296 ◽  
Author(s):  
Norihiro Mizoshita ◽  
Takao Tani ◽  
Shinji Inagaki

2011 ◽  
Vol 53 (11) ◽  
pp. 2333-2338 ◽  
Author(s):  
Yu. P. Piryatinski ◽  
A. Yu. Vakhnin ◽  
A. B. Verbitskii ◽  
A. K. Kadashchuk

2017 ◽  
Vol 56 (8) ◽  
pp. 2162-2165 ◽  
Author(s):  
Stefanie Herbst ◽  
Bartolome Soberats ◽  
Pawaret Leowanawat ◽  
Matthias Lehmann ◽  
Frank Würthner

2020 ◽  
Vol 56 (90) ◽  
pp. 14015-14018
Author(s):  
Matthias Lehmann ◽  
Markus Hecht ◽  
Stefanie Herbst ◽  
Kang Cui ◽  
Frank Würthner

A completely nanosegregated multilayer liquid crystal phase is found for a mesogen tethered perylene bisimide – a design which opens the way to new complex multifunctional materials.


2021 ◽  
Author(s):  
Rebecca Renner ◽  
Matthias Stolte ◽  
Julia Heitmüller ◽  
Tobias Brixner ◽  
Christoph Lambert ◽  
...  

Perylene-3,4:9,10-bis(dicarboximides) (PBIs) rank among the most important functional dyes and organic semiconductors but only recently their radical anions and dianions attracted interest for a variety of applications. Here, we systematically...


Soft Matter ◽  
2018 ◽  
Vol 14 (32) ◽  
pp. 6737-6744 ◽  
Author(s):  
Mingguang Zhu ◽  
Yunxiang Chen ◽  
Xiaoyi Zhang ◽  
Meihui Chen ◽  
Hongyu Guo ◽  
...  

A novel perylene bisimide (PBI) derivative with an AIE-active diphenylacrylonitrile unit positioned at the terminal N-imide position through a flexible spacer has been synthesized and characterized.


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